Kinetic Features of the Radical Polymerization of Methyl Methacrylate under Conditions of Nitroxide-Mediated Reversible Inhibition

Zaremski M. Yu.; Odintsova V. V.

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Kinetic Features of the Radical Polymerization of Methyl Methacrylate under Conditions of Nitroxide-Mediated Reversible Inhibition

机译：硝基氧化物介导的可逆抑制条件下甲基丙烯酸甲酯自由基聚合的动力学特征

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This review summarizes our and published data on the kinetics and mechanism of controlled radical polymerization of methacrylates mediated by nitroxide radicals. The reasons influencing the possibility or impossibility of the realization of radical polymerization of methyl methacrylate in the mode of reversible inhibition are analyzed. The main factors determining the specificity of the nitroxide-mediated polymerization of methacrylates are the interaction of nitroxides with growing radicals by the disproportionation mechanism, the Fischer hypereffect, a high rate of reinitiation, and an abnormally low rate of reversible termination.

机译：本文综述了我们和已发表的关于氮氧自由基介导的甲基丙烯酸酯可控自由基聚合动力学和机理的数据。分析了以可逆抑制方式实现甲基丙烯酸甲酯自由基聚合的可能性和不可能性的原因。决定氮氧化物介导的甲基丙烯酸酯聚合特异性的主要因素是氮氧化物通过歧化机制与生长自由基的相互作用、费希尔超效应、高重新起始率和异常低的可逆终止率。

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《Polymer science, Series C》 |2021年第1期|共18页
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Zaremski M. Yu.; Odintsova V. V.;
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Moscow MV Lomonosov State Univ Fac Chem Moscow 119991 Russia;

Moscow MV Lomonosov State Univ Fac Chem Moscow 119991 Russia;

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正文语种 eng
中图分类有机化学;
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1. Kinetics of Atom Transfer Radical Polymerization of Methyl Methacrylate Initiated by Cellulose Chloroacetate in BMIMCI [J] . LIN Chun-xiang, ZHAN Huai-yu, LIU Ming-hua, 高等学校化学研究：英文版 . 2013,第001期
2. Kinetics of Atom Transfer Radical Polymerization of Methyl Methacrylate Initiated by Cellulose Chloroacetate in BMIMCI [J] . LIN Chun-xiang, ZHAN Huai-yu, LIU Ming-hua, 高等学校化学研究（英文版） . 2013,第001期
3. Atom transfer radical polymerization of methyl acrylate, methyl methacrylate and styrene in the presence of trolamine as a highly effective promoter [J] . Qiao Xu, Yi-Feng Zhu, Zhao Yuan, 中国化学快报（英文版） . 2015,第006期
4. Kinetic Features of Elementary Events in the Radical Polymerization of Methyl Methacrylate under Conditions of Nitroxide-Mediated Reversible Inhibition [J] . Zaremski M. Yu., Odintsova V. V. Polymer Science, Series B. Chemistry . 2020,第1期

机译：甲基丙烯酸甲酯在氮氧化物介导的可逆抑制条件下基本事件的动力学特征
5. Kinetic features of pseudoliving radical polymerization under conditions of reversible inhibition by nitroxide radicals [J] . Zaremski M. Yu. Polymer science, Series C . 2015,第1期

机译：氮自由基可逆抑制条件下拟活性自由基聚合的动力学特征
6. Controlled synthesis of random, block-random and gradient styrene, methyl methacrylate and acrylonitrile Terpolymers via Nitroxide-mediated free radical polymerization [J] . Zaremski Mikhail, Eremeev Innokentiy, Garina Elizaveta, Journal of Polymer Research . 2017,第9期

机译：通过硝基氧化物介导的自由基聚合控制随机，嵌段随机和梯度苯乙烯，甲基丙烯酸甲酯和丙烯腈三聚合物的合成
7. Polymerization Inhibition of PoIy(Methyl Methacrylate) by Rifampin Through a Radical Scavenging Mechanism [C] . Grahmm A. Funk, Kimberly A. Cole, Elizabeth M. Horn, Society for Biomaterials annual meeting and exposition . 2018

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8. Anionic synthesis of highly isotactic polystyrene in the presence of lithium hydroxides or lithium alkoxides, and, Controlled "living" emulsion polymerization of methyl methacrylate by atom transfer radical polymerization. [D] . Makino, Takayuki. 1997

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9. Thermal Degradation Kinetics and Viscoelastic Behavior of Poly(Methyl Methacrylate)/Organomodified Montmorillonite Nanocomposites Prepared via In Situ Bulk Radical Polymerization [O] . Alexandros K. Nikolaidis, Dimitris S. Achilias 2018

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10. Mechanism and Kinetics of RAFT-Based Living Radical Polymerizations of Styrene and Methyl Methacrylate (ORGANIC MATERIALS CHEMISTRY-Polymeric Materials) [O] . Goto Atsushi, Sato Koichi, Tsujii Yoshinobu, 2001

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11. Azo Polymers for Reversible Optical Storage. 5. Orientation and DipolarInteractions of Azobenzene Side Groups in Copolymers and Blends Containing Methyl Methacrylate Structural Units [R] . Brown, D., Natansohn, A., Rochon, P. 1995

机译：用于可逆光存储的偶氮聚合物。 5.含有甲基丙烯酸甲酯结构单元的共聚物和共混物中偶氮苯侧基的取向和偶极相互作用

Kinetic Features of the Radical Polymerization of Methyl Methacrylate under Conditions of Nitroxide-Mediated Reversible Inhibition

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