An Azo-bridged Triazole Derived from Tetrazine

Qiong Yu; Richard J. Staples; Jeanne M. Shreeve

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An Azo-bridged Triazole Derived from Tetrazine

机译：富含四嗪的偶氮桥桥

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摘要

A new approach to the synthesis of 5,5'-dinitro-3,3'-azo- 1H-1,2,4-triazole (3) starting from 3,6-dihydrazinyl-1,2,4,5-tetrazine (DHT) was discovered. Nitrogen-rich energetic salts of 3 were synthesized in high yields. It is unusual that all the salts were less thermally stable than the neutral compound 3. Of all the compounds, the decomposition temperature of 217 °C, as well as being insensitive towards impact and friction, which suggests potential application as an environmentally friendly nitrogen-rich energetic material.

机译：发现了以3,6-二肼基-1,2,4,5-四嗪（DHT）为原料合成5,5'-二硝基-3,3'-偶氮-1H-1,2,4-三唑（3）的新方法。高收率合成了富氮含能盐3。不同寻常的是，所有这些盐的热稳定性都不如中性化合物3。在所有化合物中，其分解温度为217°C，并且对冲击和摩擦不敏感，这表明其作为一种环境友好的富氮含能材料具有潜在的应用前景。

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来源
《Zeitschrift fur Anorganische und Allgemeine Chemie》 |2020年第22期|共6页
作者
Qiong Yu; Richard J. Staples; Jeanne M. Shreeve;
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作者单位

Department of Chemistry University of Idaho Moscow ID 83844–2343 USA;

Department of Chemistry Michigan State University East Lansing MI 48824 USA;

Department of Chemistry University of Idaho Moscow ID 83844–2343 USA;

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原文格式 PDF
正文语种 eng
中图分类化学;
关键词
Decomposition temperature; Energetic salts; Heterocycles; Azo-bridged; Nitration;

机译：分解温度;能量盐;杂环;偶氮桥;硝化;

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3. Synthesis of 1,2,3,4-tetrazine 1,3-dioxides annulated with 1,2,3-triazoles and 1,2,3-triazole 1-oxides [J] . Alexey A. Voronin, Victor P. Zelenov, Aleksandr M. Churakov, Tetrahedron . 2014,第18期

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5. Molecular design of energetic tetrazine-triazole derivatives [J] . Li Yi, Li Yanyue, Jin Shaohua, Journal of molecular modeling . 2021,第3期

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7. Diels-Alder reactions of [60]fullerene with 1,2,4,5-tetrazines and additions to [60]fullerene-tetrazine monoadducts. [D] . Tetreau, Mark Christopher. 2002

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8. Synthesis of Novel Triazoles Tetrazine Thiadiazoles and Their Biological Activities [O] . Mohammed A. Al-Omair, Abdelwahed R. Sayed, Magdy M. Youssef 2015

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机译：1,2,3,4-四嗪，1,2,3,4-四嗪二-N-氧化物，戊唑衍生物，哒嗪聚-N-氧化物和硝基乙炔的合成

An Azo-bridged Triazole Derived from Tetrazine

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