A Coordination Polymer based on Interconnection of Thioantimonate(III) and [Mn(terpy)]~(2+) Complexes: Synthesis, Crystal Structure, and Properties of {[(Mn(terpy))_2Sb_4S_8]·0.5H_2O}_n

Felix Danker; Carolin Anderer; Christian N?ther; Huayna Terraschke; Wolfgang Bensch

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A Coordination Polymer based on Interconnection of Thioantimonate(III) and [Mn(terpy)]~(2+) Complexes: Synthesis, Crystal Structure, and Properties of {[(Mn(terpy))_2Sb_4S_8]·0.5H_2O}_n

机译：基于硫代铵（III）和[Mn（Terpy）]〜（2+）复合物的互连的配位聚合物：合成，晶体结构和{[（Mn（Terpy））_ 2SB_4S_8]·0.5H_2O} _N

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Applying Schlippe's salt, Na_3SbS_4·9H_2O, in the presence of the in-situ formed [Mn(terpy)]~(2+) complex (terpy = 2,2':6',2"-terpyridine) the new compound {[(Mn(terpy))_2Sb_4S_8]·0.5H_2O}_n (I) could be obtained under solvothermal conditions. Interestingly, in the crystal structure the two unique Mn~(2+) cations adopt different environments to form a MnN_3S_3 octahedron and a MnN_3S_2 trigonal pyramid. The trigonal pyramidal SbS_3 ~(3-) anions share common edges yielding a Sb_8S_8 ring. Covalent bonds between Mn~(2+) and S~(2-) generate MnSb_2S_3 and Mn_2Sb_4S_6 heterocycles. The Sb_8S_8 and Mn_2Sb_4S_6 rings are condensed to form a chain. The MnN_3S_3 octahedron and the MnN_3S_2 polyhedron share a common S~(2-) anion and antiferromagnetic properties are observed mediated by superexchange interactions. {[(Mn(terpy))_2Sb_4S_8]·0.5H_2O}_n shows luminescence in the blue-green spectral range, assigned to combined contributions from Mn~(2+) ions and from the organic ligand.

机译：使用Schlippe盐Na_3SbS_4·9H_2O，在溶剂热条件下，在原位形成的[Mn（terpy）]~（2+）配合物（terpy=2,2'：6'，2”-三吡啶）的存在下，可以得到新化合物{[（Mn（terpy））2Sb_4Su8]·0.5H_2O}n（I）。有趣的是，在晶体结构中，两种独特的Mn~（2+）离子采用不同的环境形成MnN_3S_3八面体和MnN_3S_2三角棱锥阴离子共享公共边，形成Sb_8S_8环。Mn~（2+）和S~（2-）之间的共价键生成MnSb_2S_3和Mn_2Sb_4S_6杂环。Sb_8S_8和Mn_2Sb_4S_6环被浓缩成链。MnN_3S_3八面体和MnN_3S_2多面体共享一个共同的S~（2-）阴离子，并通过超交换作用观察到反铁磁性质。{[（Mn（terpy））_2Sb_4S_8]·0.5H_2O}_n在蓝绿色光谱范围内显示发光，分配给来自Mn~（2+）离子和有机配体的组合贡献。

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来源
《Zeitschrift fur Anorganische und Allgemeine Chemie》 |2020年第13期|共7页
作者
Felix Danker; Carolin Anderer; Christian N?ther; Huayna Terraschke; Wolfgang Bensch;
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Institut für Anorganische Chemie Christian-Albrechts-Universit?t zu Kiel Max-Eyth-Str. 2 24118 Kiel Germany;

Institut für Anorganische Chemie Christian-Albrechts-Universit?t zu Kiel Max-Eyth-Str. 2 24118 Kiel Germany;

Institut für Anorganische Chemie Christian-Albrechts-Universit?t zu Kiel Max-Eyth-Str. 2 24118 Kiel Germany;

Institut für Anorganische Chemie Christian-Albrechts-Universit?t zu Kiel Max-Eyth-Str. 2 24118 Kiel Germany;

Institut für Anorganische Chemie Christian-Albrechts-Universit?t zu Kiel Max-Eyth-Str. 2 24118 Kiel Germany;

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正文语种 eng
中图分类化学;
关键词
Solvothermal synthesis; Manganese thioantimonate; Manganese; Magnetic properties; Luminescence;

机译：溶剂质合成;锰硫代铵;锰;磁性;发光;

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A Coordination Polymer based on Interconnection of Thioantimonate(III) and [Mn(terpy)]~(2+) Complexes: Synthesis, Crystal Structure, and Properties of {[(Mn(terpy))_2Sb_4S_8]·0.5H_2O}_n

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