Facile Synthesis of MOF-derived Mn_3O_4@N-doped Carbon with Efficient Oxygen Reduction

Li Xiao; Jie Yuan; Hai-Bin Zhu

首页> 外文期刊>Zeitschrift fur Anorganische und Allgemeine Chemie >Facile Synthesis of MOF-derived Mn_3O_4@N-doped Carbon with Efficient Oxygen Reduction

【24h】

Facile Synthesis of MOF-derived Mn_3O_4@N-doped Carbon with Efficient Oxygen Reduction

机译：具有高效氧还原的MOF衍生MN_3O_4 @ n掺杂碳的体积合成

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

Integration of MnO_x into the carbon matrix proves a viable strategy to improve the electrochemical performance of MnO_x materials. Mn_3O_4 nanoparticle-decorated N-doped carbon composites (Mn_3O_4@N-doped carbon) were facilely prepared from a non-porous eight-fold interpenetrated Zn~(II)-based MOF, which involves first synthesis of bimetallic Mn/Zn-MOF in one-pot reaction followed by direct pyrolysis at 1000 °C. In 0.1 m KOH solution, the optimal Mn_3O_4@Ndoped carbon exhibits decent oxygen reduction activity with the onset potential (E_(onset)) of 0.94 V (vs. RHE) and half-wave potential (E_(1/2)) of 0.81 V (vs. RHE), excellent methanol tolerance as well as good durability.

机译：将MnO_x集成到碳基体中证明了一种改善MnO_x材料电化学性能的可行策略。Mn_3O_4纳米粒子修饰的掺氮碳复合材料（Mn_3O_4@N-用无孔八重互穿Zn~（II）基MOF方便地制备了掺杂碳，该MOF首先在一锅反应中合成双金属Mn/Zn MOF，然后在1000°C下直接热解。在0.1M KOH溶液中，最佳的Mn_3O_4@Ndoped碳表现出良好的氧还原活性，起始电位（E_（起始））为0.94 V（vs.RHE），半波电位（E_（1/2））为0.81 V（vs.RHE），具有优异的耐甲醇性和良好的耐久性。

著录项

来源
《Zeitschrift fur Anorganische und Allgemeine Chemie》 |2020年第17期|共6页
作者
Li Xiao; Jie Yuan; Hai-Bin Zhu;
展开▼
作者单位

School of Chemistry and Chemical Engineering Southeast University Nanjing 211189 P. R. China;

School of Chemistry and Chemical Engineering Southeast University Nanjing 211189 P. R. China;

School of Chemistry and Chemical Engineering Southeast University Nanjing 211189 P. R. China;

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类化学;
关键词
Oxygen reduction; Manganese oxide; Manganese; N-doped carbon; Interpenetrated MOFs;

机译：氧还原;氧化锰;锰;N-掺杂碳;渗透的MOF;

相似文献

外文文献
中文文献
专利

1. Controllable active sites and facile synthesis of cobalt nanoparticle embedded in nitrogen and sulfur co-doped carbon nanotubes as efficient bifunctional electrocatalysts for oxygen reduction and evolution reactions [J] . Taeseob Oh, Kwanwoo Kim, Jooheon Kim 能源化学：英文版 . 2019,第011期
2. Controllable active sites and facile synthesis of cobalt nanoparticle embedded in nitrogen and sulfur co-doped carbon nanotubes as efficient bifunctional electrocatalysts for oxygen reduction and evolution reactions [J] . Taeseob Oh, Kwanwoo Kim, Jooheon Kim 天然气化学（英文版） . 2019,第011期
3. Facile Synthesis of N-Doped Graphene-Like Carbon Nanoflakes as Efficient and Stable Electrocatalysts for the Oxygen Reduction Reaction [J] . Daguo Gu, Yao Zhou, Ruguang Ma, 纳微快报：英文版 . 2018,第002期
4. A facile template approach for the synthesis of mesoporous Fe3C/Fe-N-doped carbon catalysts for efficient and durable oxygen reduction reaction [J] . Shuai Li, Bo Li, Liang Ma, 中国化学快报（英文版） . 2017,第011期
5. A facile synthesis of hierarchically porous carbon derived from serum albumin by a generated-templating method for efficient oxygen reduction reaction [J] . Xiaobin Cai, Hanyu Li, Xinliang Guo, RSC Advances . 2020,第65期

机译：通过产生的模板衍生自血清白蛋白的分层多孔碳的容纳合成，用于高效氧还原反应
6. Facile synthesis of polyacrylonitrile-based N/S-codoped porous carbon as an efficient oxygen reduction electrocatalyst for zinc-air batteries [J] . Li Guodong, Pei Lei, Wu Yu, Journal of Materials Chemistry, A. Materials for energy and sustainability . 2019,第18期

机译：基于聚丙烯腈的N / S编码多孔碳的容易合成作为锌 - 空气电池有效的氧还原电催化剂
7. Facile synthesis of magnesium ferrite nanoparticles supported on nitrogen and sulfur co-doped carbon black as an efficient electrocatalyst for oxygen reduction reaction [J] . Kiani Maryam, Zhang Jie, Chen Jinwei, Journal of nanoparticle research: An interdisciplinary forum for nanoscale science and technology . 2019,第5期

机译：镁铁氧体纳米粒子的容纳合成氮气和硫磺共掺杂炭黑作为氧还原反应有效电催化剂
8. FACILE ROUTE TO BIMETAL AND NITROGEN-CODOPED 3D POROUS GRAPHITIC CARBON NETWORKS FOR EFFICIENT OXYGEN REDUCTION [C] . Feng Wang, Zhengping Zhang, Meiling Dou World Conference on Carbon . 2016

机译：用于双金属和氮气编排的3D多孔石墨碳网络的容易途径，用于有效氧气减少
9. A facile synthesis of highly stable modified carbon nanotubes as efficient oxygen reduction reaction catalysts. [D] . Stacy, John M. 2016

机译：轻松合成高度稳定的改性碳纳米管作为有效的氧还原反应催化剂。
10. Facile Synthesis of the Amorphous Carbon Coated Fe-N-C Nanocatalyst with Efficient Activity for Oxygen Reduction Reaction in Acidic and Alkaline Media [O] . Linglei Jin, Baikang Zhu, Xuesong Wang, 2020

机译：无定形碳涂层Fe-N-C纳米催化剂的容易合成具有耐氧和碱性介质中氧还原反应的有效活性
11. Facile Synthesis of the Amorphous Carbon Coated Fe-N-C Nanocatalyst with Efficient Activity for Oxygen Reduction Reaction in Acidic and Alkaline Media [O] . Linglei Jin, Baikang Zhu, Xuesong Wang, 2020

机译：无定形碳涂层Fe-N-C纳米催化剂的容易合成，具有耐氧和碱性介质中氧还原反应的有效活性
12. Metal-free and Oxygen-free Graphene as Oxygen Reduction Catalysts for Highly Efficient Fuel Cells. [R] . J. Baek L. Dai 2013

机译：无金属和无氧石墨烯作为高效燃料电池的氧还原催化剂。

Facile Synthesis of MOF-derived Mn_3O_4@N-doped Carbon with Efficient Oxygen Reduction

摘要

著录项

相似文献

相关主题

期刊订阅