Synthesis and structural characterization of Mn(II) and Cu(II) complexes with bis(4-(1H-imidazol-1-yl)phenyl)methanone ligands

Wang Gao-Feng; Zhang Xiao; Liu Zhao-Rong; Wang Yu-Chun; Jiang Hong-Shi; Li Mei-Zhuan; Jiao Jiao; Ma Hui-Xuan; Jiang Xiu-Ping; Han Qiu-Ping

首页> 外文期刊>Zeitschrift fur Naturforschung, B. A Journal of Chemical Sciences >Synthesis and structural characterization of Mn(II) and Cu(II) complexes with bis(4-(1H-imidazol-1-yl)phenyl)methanone ligands

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Synthesis and structural characterization of Mn(II) and Cu(II) complexes with bis(4-(1H-imidazol-1-yl)phenyl)methanone ligands

机译：用双（4-（1H-（1H-咪唑-1-基）苯基）甲基酮配体的Mn（II）和Cu（II）配合物的合成及结构表征

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Two complexes, {Mn(hfac)(2)(BIPMO)}(n) (1), {Cu(hfac)(2)(BIPMO)}(n) (2) [hfac = 1,1,1,5,5,5-hexafluoropentane-2,4-dionato(-), BIPMO = bis(4-(1H-imidazol-1-yl)phenyl)methanone], with the V-shaped ligands were synthesized and characterized by infrared spectroscopy, elemental analyses, along with single-crystal X-ray diffraction analyses. The X-ray diffraction studies have shown that the metal ions in 1 and 2 are both six-coordinated to two nitrogen atoms of two BIPMO ligands and four oxygen atoms of two hfac ligands to form a distorted octahedral geometry. Each BIPMO ligand acts as a bridging ligand to link two adjacent metal(II) atoms to form a helical chain in the crystal structure.

机译：合成了两种配合物，{Mn（hfac）（2）（BIPMO）}（n）（1），{Cu（hfac）（2）（BIPMO）}（n）（2）[hfac=1,1,1,5,5,5-六氟戊烷-2,4-二氧基（-），BIPMO=双（4-（1H-咪唑-1-基）苯基）甲酮]，并通过红外光谱、元素分析和单晶X射线衍射分析对其进行了表征。X射线衍射研究表明，1和2中的金属离子均与两个BIPMO配体的两个氮原子和两个hfac配体的四个氧原子六配位，形成扭曲的八面体几何形状。每个BIPMO配体充当桥接配体，连接两个相邻的金属（II）原子，在晶体结构中形成螺旋链。

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来源
《Zeitschrift fur Naturforschung, B. A Journal of Chemical Sciences》 |2017年第1期|共5页
作者
Wang Gao-Feng; Zhang Xiao; Liu Zhao-Rong; Wang Yu-Chun; Jiang Hong-Shi; Li Mei-Zhuan; Jiao Jiao; Ma Hui-Xuan; Jiang Xiu-Ping; Han Qiu-Ping;
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作者单位

Yuncheng Univ Dept Appl Chem Yuncheng 044000 Peoples R China;

Harbin Inst Technol MIIT Key Lab Crit Mat Technol New Energy Convers Sch Chem &

Chem Engn Harbin 150080 Peoples R China;

Yuncheng Univ Dept Appl Chem Yuncheng 044000 Peoples R China;

Yuncheng Univ Dept Appl Chem Yuncheng 044000 Peoples R China;

Yuncheng Univ Dept Appl Chem Yuncheng 044000 Peoples R China;

Yuncheng Univ Dept Appl Chem Yuncheng 044000 Peoples R China;

Yuncheng Univ Dept Appl Chem Yuncheng 044000 Peoples R China;

Yuncheng Univ Dept Appl Chem Yuncheng 044000 Peoples R China;

Yuncheng Univ Dept Appl Chem Yuncheng 044000 Peoples R China;

Yuncheng Univ Dept Appl Chem Yuncheng 044000 Peoples R China;

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正文语种 eng
中图分类化学;
关键词
benzophenone; bidentate ligand; coordination polymer; helical chain; N-donor ligands;

机译：二苯甲酮;二齿配体;配位聚合物;螺旋链;N-供体配体;

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Synthesis and structural characterization of Mn(II) and Cu(II) complexes with bis(4-(1H-imidazol-1-yl)phenyl)methanone ligands

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