Synthesis and application of methylthio-substituted BODIPYs/ aza-BODIPYs

Jiang Xin-Dong; Liu Xin; Fang Tao; Sun Changliang

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Synthesis and application of methylthio-substituted BODIPYs/ aza-BODIPYs

机译：甲基羟基吡吡普（甲基硫磷酸）/ AZA-BODIPYS的合成与应用

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A series of new BODIPYs/aza-BODIPYs with a methylthio group Were Herein prepared. Introduction of the electron-donating methylthio substituent into such dyes could reduce the fluorescence quantum yield, red-shift its emission spectra, provide higher extinction coefficients and larger Stokes' shift. Oxidation of the thioether of BODIPY 4 into the corresponding electron -withdrawing sulfoxide by HC10 can restore the quantum yield and blue-shift its emission spectra, and dye 4 was highly sensitive and selective to HCIO. (C) 2017 Elsevier Ltd. All rights reserved.

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来源
《Dyes and Pigments》 |2017年第2017期|共7页
作者
Jiang Xin-Dong; Liu Xin; Fang Tao; Sun Changliang;
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作者单位

Shenyang Univ Chem Technol Coll Appl Chem Shenyang 110142 Liaoning Peoples R China;

Shenyang Univ Chem Technol Coll Appl Chem Shenyang 110142 Liaoning Peoples R China;

Shenyang Univ Chem Technol Coll Appl Chem Shenyang 110142 Liaoning Peoples R China;

Shenyang Univ Chem Technol Ctr Phys &

Chem Test Shenyang 110142 Liaoning Peoples R China;

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原文格式 PDF
正文语种 eng
中图分类染料及中间体工业;颜料工业;
关键词
Aza-BODIPY; NIR; Fluorescent dye; Methylthio; Oxidation;

机译：Aza-Bodipy;尼尔;荧光染料;甲基硫胺;氧化;

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专利

1. Synthesis of aza-BODIPY dyes bearing the naphthyl groups at 1,7-positions and application for singlet oxygen generation [J] . Xindong Jiang, Tingjiang Zhang, Changliang Sun, 中国化学快报（英文版） . 2019,第005期
2. Water-soluble BODIPY and aza-BODIPY dyes： synthetic progress and applications [J] . Gang FANt, Le YANG, Zhijian CHEN 化学科学与工程前沿：英文版 . 2014,第004期
3. Synthesis and application of methylthio-substituted BODIPYs/ aza-BODIPYs [J] . Jiang Xin-Dong, Liu Xin, Fang Tao, Dyes and Pigments . 2017,第期

机译：甲基羟基吡吡普（甲基硫磷酸）/ AZA-BODIPYS的合成与应用
4. Thieno[1,3,2]oxazaborinine-containing aza-BODIPYs with near infrared absorption bands: synthesis, photophysical properties, and device applications [J] . Kubo Yuji, Shimada Takuma, Maeda Kentaro, New Journal of Chemistry . 2020,第1期

机译：Thieno [1,3,2]含有近红外吸收带的含氧氮杂氨醌的AZA-Bodipys：合成，光药性和器件应用
5. Synthesis and application of near-infrared absorbing morpholino-containing aza-BODIPYs [J] . Jiang Xin-Dong, Jia Lei, Su Yajun, Tetrahedron . 2019,第33期

机译：含近红外吸收的含上的AZA-BODIPYS的合成与应用
6. SYNTHESIS OF GLYCOCONJUGATED AZA-BODIPYS FOR PHOTODYNAMIC THERAPY [C] . Tobias Zweibohmer, Thomas Ziegler International Carbohydrate Symposium . 2018

机译：用于光动力疗法的甘油缀合的AZA-BODIPYS的合成
7. Synthesis and Characterization of Novel Ferrocene Containing aza-BODIPY and Porphyrin Compounds [D] . Holstrom, Cole Dante. 2016

机译：新型含氮杂-BODIPY和卟啉化合物的二茂铁的合成与表征
8. Aza-BODIPY: improved synthesis and interaction with soluble Aβ1-42 oligomers [O] . Laramie P. Jameson, Sergei V. Dzyuba -1

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9. Synthesis, structure and photophysical properties of NIR aza-BODIPYs with -F/-N-3/NH2 groups at 1,7-positions [O] . Jiang, Xin-Dong, Guan, Jian, Zhao, Jiuli, 2017

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10. Tandem Reduction/Cyclization of O-Nitrophenyl Propargyl Alcohols-A Novel Synthesis of 2- & 2,4-Disubstituted Quinolines and Application to the Synthesis of Streptonigrin; Doctoral thesis [R] . Sandelier, M. J. 2008

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Synthesis and application of methylthio-substituted BODIPYs/ aza-BODIPYs

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