An efficient hydration of nitriles with ruthenium-supported heterogeneous catalyst in water under moderate conditions

Hussain Muhammad Asif; Choi Eun Ju; Maqbool Adnan; Atif Muhammad; Zeb Hassan; Yeo JaeGoo; Yu Jung-A; Cho Yong-Hun; Noh Moses; Kim Jung Won

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An efficient hydration of nitriles with ruthenium-supported heterogeneous catalyst in water under moderate conditions

机译：在中等条件下，在水中具有钌 - 载体的非均相催化剂的高效水合

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A facile eco-friendly heterogeneous catalytic system has been developed for amide synthesis that further utilized in pharmaceutical and organic chemistry. The Ru/MnO2 catalyst has shown outstanding and unprecedented activity for a wide range of aliphatic and benzylic nitriles in green solvent water at 60 degrees C. The system has also exhibited a remarkable tolerance for selective hydration of heteroatom (e.g. nitrogen, oxygen and sulphur atoms) containing nitriles. Pharmaceutically important nicotinamides and pyrazinamide has been synthesized by hydration of the heteroatomic nitriles with appreciable yields and selectivities. Moreover, the Ru/MnO2 catalyst has employed water as a benign solvent, with more than 30,000 TONs and reusability five times after isolation from the reaction mixture by centrifugation and easy workup that established a path for green environmental and technologically acceptable protocol. (C) 2021 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.

机译：开发了一种简便、环保的多相催化体系用于酰胺合成，并进一步应用于医药和有机化学。Ru/MnO2催化剂在60℃下对绿色溶剂水中的各种脂肪族和苄基腈表现出了卓越且前所未有的活性。该系统还表现出对含腈的杂原子（例如氮、氧和硫原子）选择性水合的显著耐受性。通过异原子腈的水合反应合成了具有重要药用价值的烟酰胺和吡嗪酰胺，具有可观的产率和选择性。此外，Ru/MnO2催化剂使用水作为一种良性溶剂，通过离心和简单的处理从反应混合物中分离出来后，可重复使用5次，超过30000吨，为绿色环保和技术上可接受的方案开辟了道路。（2021）韩国工业和工程化学学会。由爱思唯尔B.V.出版。版权所有。

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来源
《Journal of industrial and engineering chemistry》 |2021年第1期|共9页
作者
Hussain Muhammad Asif; Choi Eun Ju; Maqbool Adnan; Atif Muhammad; Zeb Hassan; Yeo JaeGoo; Yu Jung-A; Cho Yong-Hun; Noh Moses; Kim Jung Won;
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作者单位

Univ Engn &

Technol Dept Met &

Mat Engn Lahore 39161 Pakistan;

Kangwon Natl Univ Dept Chem Engn Samcheok 25913 Gangwon Do South Korea;

Univ Engn &

Technol Dept Met &

Mat Engn Lahore 39161 Pakistan;

Univ Educ Lahore DS&

T Dept Chem Vehari Campus Punjab Pakistan;

Univ Punjab Inst Energy &

Environm Engn Lahore Pakistan;

Kangwon Natl Univ Dept Chem Engn Samcheok 25913 Gangwon Do South Korea;

Kangwon Natl Univ Dept Chem Engn Samcheok 25913 Gangwon Do South Korea;

Kangwon Natl Univ Dept Chem Engn Samcheok 25913 Gangwon Do South Korea;

Drexel Univ Dept Mech Engn &

Mech 3141 Chestnut St Philadelphia PA 19104 USA;

Kangwon Natl Univ Dept Chem Engn Samcheok 25913 Gangwon Do South Korea;

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原文格式 PDF
正文语种 eng
中图分类化学工业;
关键词
Ruthenium; Manganese oxide; Hydration; Water; Nitrile; Amide;

机译：None;

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2. Fe3O4/ZnS Hollow Nanospheres:A Highly Efficient Magnetic Heterogeneous Catalyst for Synthesis of 5-Substituted 1H-Tetrazoles from Nitriles and Sodium Azide [J] . Qi Gang, Liu Wei, Bei Zhining 中国化学（英文版） . 2011,第001期
3. Novel HBD-Containing Zn (dobdc) (datz) as efficiently heterogeneous catalyst for CO_(2) chemical conversion under mild conditions [J] . Jianwen Lan, Ye Qu, Ping Xu, 绿色能源与环境：英文版 . 2021,第001期
4. Novel HBD-Containing Zn(dobdc)(datz)as efficiently heterogeneous catalyst for CO2 chemical conversion under mild conditions [J] . Jianwen Lan, Ye Qu, Ping Xu, 绿色能源与环境（英文） . 2021,第001期
5. A General and Efficient Heterogeneous Gold-Catalyzed Hydration of Nitriles in Neat Water under Mild Atmospheric Conditions [J] . Liu Yong-Mei, He Lin, Wang Miao-Miao, ChemSusChem . 2012,第8期

机译：轻度大气条件下纯净水中腈中腈的一般和高效的非均相金催化水合
6. An efficient ruthenium(ⅳ) catalyst for the selective hydration of nitriles to amides in water under mild conditions [J] . Eder Tomas-Mendivil, Francisco J. Suarez, Josefina Diez, Chemical Communications . 2014,第68期

机译：在温和的条件下将腈选择性水合为酰胺的高效钌（ⅳ）催化剂
7. A Heterogeneous Ruthenium dmso Complex Supported onto Silica Particles as a Recyclable Catalyst for the Efficient Hydration of Nitriles in Aqueous Medium [J] . Manrique Ester, Ferrer Ingrid, Lu Changyong, Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2019,第13期

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8. Silica Supported Barium Chloride (SiO2-BaCl2): Efficient and Heterogeneous catalyst for the environmentally friendly preparation of N,N′-alkylidene bisamides under solvent-free condition [C] . 2nd International Conference on Chemical, Biological and Environmental Engineering . 2010

机译：二氧化硅负载的氯化钡（SiO 2 -BaCl 2 ）：高效，多相催化剂，可在无溶剂条件下环保地制备N，N'-亚烷基双酰胺
9. Synthesis and Coordination Chemistry of Novel Water Soluble Diphosphines: Application to Ruthenium Catalyzed Aqueous Nitrile Hydration [D] . Sears, Jeremiah M. 2012

机译：新型水溶性二膦的合成与配位化学：在钌催化的丁腈水合中的应用
10. An efficient heterogeneous catalyst (CuO@ARF) for on-water C-S coupling reaction: an application to the synthesis of phenothiazine structural scaffold [O] . Debasish Sengupta, Basudeb Basu 2014

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11. A Heterogeneous Ruthenium dmso Complex Supported onto Silica Particles as a Recyclable Catalyst for the Efficient Hydration of Nitriles in Aqueous Medium [O] . -1

机译：一种非均相的钌DMSO复合物，其在二氧化硅颗粒上作为含水介质中腈的有效水化的可回收催化剂
12. Kinetics and Mechanism of Nitrile Hydration Catalyzed by Unhindered Hydridobis(phosphine)platinum(II) Complexes. Regioselective Hydration of Acrylonitrile [R] . Jensen, C. M., Trogler, W. C. 1986

机译：无阻氢化膦（磷）铂（Ⅱ）配合物催化腈水合反应动力学及机理。丙烯腈的区域选择性水合

An efficient hydration of nitriles with ruthenium-supported heterogeneous catalyst in water under moderate conditions

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