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首页> 外文期刊>Journal of Phase Equilibria and Diffusion >Phase Equilibria of the Mg-Gd-Ce System at 500 degrees C
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Phase Equilibria of the Mg-Gd-Ce System at 500 degrees C

机译:500摄氏度的Mg-GD-CE系统的相平衡

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摘要

The phase equilibria of the Mg-Gd-Ce system at 500 degrees C were investigated by means of the electron probe microanalysis (EPMA) and x-ray diffraction (XRD) on equilibrated alloys. The existence of the so-called normal tetragonal CeMg12(I) and long-range ordered CeMg12(II) was confirmed in the present work. The following five three-phase equilibria were well determined: (1) (Mg) + CeMg12(I) + Ce5Mg41, (2) (Mg) + Ce5Mg41 + GdMg5, (3) Ce5Mg41 + GdMg5 + (Ce,Gd)Mg-3, (4) (Ce,Gd)Mg-3 + GdMg2 + (Ce,Gd)Mg and (5) (Ce,Gd)Mg + (delta Ce) + (beta Ce). The solubility of Ce in GdMg5 and in GdMg2 was measured to be 7.8 and 8.7 at.% Ce, respectively. The solubility of Gd in CeMg12(I), in Ce5Mg41 and in (delta Ce) were measured to be 1.0, 4.6 and 2.4 at.% Gd, respectively. Two continuous series of solid solutions form between GdMg3 and CeMg3, and between GdMg and CeMg. The overall isothermal section at 500 degrees C was constructed based on the present data with a few extrapolations.
机译:用电子探针(EPMA)和x射线衍射(XRD)研究了Mg-Gd-Ce体系在500℃时的相平衡。本工作证实了所谓的正常四方CeMg12(I)和长程有序CeMg12(II)的存在。以下五个三相平衡得到了很好的确定:(1)(Mg)+CeMg12(I)+Ce5Mg41,(2)(Mg)+Ce5Mg41+GdMg5,(3)Ce5Mg41+GdMg5+(Ce,Gd)Mg-3,(4)(Ce,Gd)Mg-3+GdMg2+(Ce,Gd)Mg和(5)(Ce,Gd)Mg+(δCe)+(βCe)。测得Ce在GdMg5和GdMg2中的溶解度分别为7.8和8.7 at.%分别是行政长官。Gd在CeMg12(I)、Ce5Mg41和(δCe)中的溶解度分别为1.0、4.6和2.4 at.%分别是Gd。GdMg3和CeMg3之间以及GdMg和CeMg之间形成两个连续的固溶体系列。在500℃下的整体等温截面是基于现有数据和一些外推构建的。

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