Microporous Cd(II) Metal-Organic Framework for CO2 Catalysis, Luminescent Sensing, and Absorption of Methyl Green

Wang Yao; Yang Guo-Ping; Zhang Peng-Feng; Ma Lu-Lu; Wang Jiao-Min; Li Gao-Peng; Wang Yao-Yu

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Microporous Cd(II) Metal-Organic Framework for CO2 Catalysis, Luminescent Sensing, and Absorption of Methyl Green

机译：微孔CD（II）金属有机框架用于CO2催化，发光感测和甲基绿色的吸收

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A new porous metal-organic framework (MOF) {[Cd(Hbptc)]center dot H2O}(n) (Cdbptc) was assembled by Cd(II) ions and a rigid (1,1'-biphenyl)-2,4,6-tricarboxylic acid (H(3)bptc) ligand via a solvothermal method. Cdbptc was studied by the physical and chemical analyses methods, exhibiting captivating three-dimensional (3D) microporosity with a 1D channel of 1.7 nm decorated by the uncoordinated hydroxyl groups. It is worth noting that clusters were formed by Cd(II) ions as the Lewis active sites, making it as an excellent reused homogeneous catalyst for the CO2 cycloaddition reaction. In addition, the fluorescence study of Cdbptc indicated Cr3+, Cu2+, Fe3+, [Fe(CN)(6)](3-), and Cr2O72- ions could be multiply detected with a low detection limit. Besides, the dye adsorption experiment demonstrated that methyl green (MG) dye could be selectively adsorbed by Cdbptc from other dyes, and the adsorption mechanism was testified by X-ray photoelectron spectroscopic data and Fourier transform infrared spectrum data.

机译：通过溶剂热法，用Cd（II）离子和刚性（1,1'-联苯）-2,4,6-三羧酸（H（3）配体组装了一种新的多孔金属有机骨架（MOF）{[Cd（Hbptc）]中心点H2O}（n）（Cdbptc）。Cdbptc通过物理和化学分析方法进行了研究，显示出迷人的三维（3D）微孔，由未配位羟基修饰的1D通道为1.7nm。值得注意的是，Cd（II）离子作为Lewis活性中心形成了团簇，这使其成为CO2环加成反应的优良重复使用均相催化剂。此外，Cdbptc的荧光研究表明，Cr3+、Cu2+、Fe3+、[Fe（CN）（6）]（3-）和Cr2O72-离子可以在较低的检测限下被倍增检测。此外，染料吸附实验表明，甲基绿（MG）染料可以被Cdbptc从其他染料中选择性吸附，吸附机理由X射线光电子能谱数据和傅里叶变换红外光谱数据证实。

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《Crystal growth & design》 |2021年第5期|共10页
作者
Wang Yao; Yang Guo-Ping; Zhang Peng-Feng; Ma Lu-Lu; Wang Jiao-Min; Li Gao-Peng; Wang Yao-Yu;
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Northwest Univ Coll Chem &

Mat Sci Key Lab Synthet &

Nat Funct Mol Shaanxi Key Lab Phys Inorgan Chem Minist Educ Xian 710127 Peoples R China;

Northwest Univ Coll Chem &

Mat Sci Key Lab Synthet &

Nat Funct Mol Shaanxi Key Lab Phys Inorgan Chem Minist Educ Xian 710127 Peoples R China;

Northwest Univ Coll Chem &

Mat Sci Key Lab Synthet &

Nat Funct Mol Shaanxi Key Lab Phys Inorgan Chem Minist Educ Xian 710127 Peoples R China;

Northwest Univ Coll Chem &

Mat Sci Key Lab Synthet &

Nat Funct Mol Shaanxi Key Lab Phys Inorgan Chem Minist Educ Xian 710127 Peoples R China;

Northwest Univ Coll Chem &

Mat Sci Key Lab Synthet &

Nat Funct Mol Shaanxi Key Lab Phys Inorgan Chem Minist Educ Xian 710127 Peoples R China;

Northwest Univ Coll Chem &

Mat Sci Key Lab Synthet &

Nat Funct Mol Shaanxi Key Lab Phys Inorgan Chem Minist Educ Xian 710127 Peoples R China;

Northwest Univ Coll Chem &

Mat Sci Key Lab Synthet &

Nat Funct Mol Shaanxi Key Lab Phys Inorgan Chem Minist Educ Xian 710127 Peoples R China;

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中图分类晶体学;
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1. Luminescent nanoscale metal-organic frameworks for chemical sensing [J] . Xiao-Yan Ren, Le-Hui Lu 中国化学快报（英文版） . 2015,第012期
2. A New Microporous Metal-Organic Framework for Highly Selective C2H2/CH4 and C2H2/CO2 Separation at Room Temperature [J] . Xing Duan, Tifeng Xia, Zhenguo Ji, 中国化学（英文版） . 2017,第008期
3. A Versatile Microporous Zinc(II) Metal-Organic Framework for Selective Gas Adsorption, Cooperative Catalysis, and Luminescent Sensing [J] . He Hongming, Zhang De-Yu, Guo Feng, Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2018,第12期

机译：多孔微孔锌（II）金属有机框架，用于选择性气体吸附，合作催化和发光感测
4. Resorcin[4]arene-Based Microporous Metal-Organic Framework as an Efficient Catalyst for CO2 Cycloaddition with Epoxides and Highly Selective Luminescent Sensing of Cr2O72- [J] . Lu Bing-Bing, Jiang Wei, Yang Jin, ACS applied materials & interfaces . 2017,第45期

机译：基于环氧化的基于环氧胺的基于芳烃的微孔金属 - 有机框架，其具有环氧化物的CO2环加入的有效催化剂和CR2O72的高选择性发光感测
5. Microporous Lanthanide Metal-Organic Frameworks with Multiple 1D Channels: Tunable Colors, White-Light Emission, and Luminescent Sensing for Iron(II) and Iron(III) [J] . Zhou Zhong-Yuan, Han Yun-Hu, Xing Xiu-Shuang, ChemPlusChem . 2016,第8期

机译：具有多个1D通道的微孔镧系金属 - 有机框架：用于铁（II）和铁（II）的可调色，白光发射和发光感测
6. A luminescent nano-scale metal-organic framework for sensing small molecules [C] . Hui Xu, Zhongshang Dou, Yuanjin Cui, Nanoelectronics Conference (INEC), 2010 . 2010

机译：用于感测小分子的发光纳米级金属有机框架
7. The synthesis and characterization of microporous open-framework transition metal silicates and metal-organic frameworks. [D] . Huang, Jin. 2004

机译：微孔开放骨架过渡金属硅酸盐和金属有机骨架的合成与表征。
8. Temperature dependent CO2 behavior in microporous 1-D channels of a metal-organic framework with multiple interaction sites [O] . Dongwook Kim, Jaehun Park, Yung Sam Kim, -1

机译：具有多个相互作用位点的金属-有机骨架的微孔1-D通道中温度依赖性CO2行为
9. Microporous Cd(II) MetalOrganic Framework for CO2 Catalysis, Luminescent Sensing, and Absorption of Methyl Green [O] . -1

机译：微孔CD（ii）金属有机型框架，用于CO2催化，发光感测和甲基绿色的吸收
10. Section II, A2, G-7.5 Metal-Organic Framework Materials for Force Protection. [R] . Hupp, J. T., Farha, O. K. 2018

机译：第二节，a2，G-7.5用于力保护的金属有机骨架材料。

Microporous Cd(II) Metal-Organic Framework for CO2 Catalysis, Luminescent Sensing, and Absorption of Methyl Green

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