Self-Assembled Polyoxometalate-Based Metal-Organic Polyhedra as an Effective Heterogeneous Catalyst for Oxidation of Sulfide

Hong-Mei  Gan; Chao  Qin; Liang  Zhao; Chunyi  Sun; Xing-Long  Wang; Zhong-Min  Su

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Self-Assembled Polyoxometalate-Based Metal-Organic Polyhedra as an Effective Heterogeneous Catalyst for Oxidation of Sulfide

机译：基于自组装的多氧酸酯基金属 - 有机多面体，作为氧化氧化的有效非均相催化剂

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Two polyoxovanadate-based metal-organic polyhedra with octahedral (oct ) and rhombic dodecahedral (rdo ) geometries have been constructed from a concave molecular building block and linear and triangular carboxylate ligands. VMOP-7 is constructed from {V_(5)O_(9)Cl} SBU and a linear anthracene-9,10-dicarboxylic acid ligand in which all the anthracene groups are perpendicular to the edge of the octahedron. Such an arrangement mode can effectively reduce the steric hindrance between ligands. VMOP-8 is constructed from {V_(5)O_(9)Cl} SBU and a triangular biphenyl 3,4,5-tricarboxylate ligand, which exhibits an elongated rhombic dodecahedral configuration due to the geometry of the ligand. Furthermore, VMOP-8 can serve as a heterogeneous catalyst and exhibits efficient and common catalytic activity for oxidative desulfurization.

机译：两种基于多钒酸盐的金属有机多面体具有八面体（oct）和菱形十二面体（rdo）几何形状，它们由凹面分子构建块和线性和三角形羧酸配体构成 VMOP-7由{V_5）O_9）Cl}SBU和一个线性蒽-9,10-二羧酸配体构成，其中所有蒽基团垂直于八面体的边缘。这种排列方式可以有效地减少配体之间的空间位阻 VMOP-8由{V_5）O_9）Cl}SBU和三角形联苯3,4,5-三羧酸配体构成，由于配体的几何形状，该配体呈现细长的菱形十二面体构型。此外，VMOP-8可以作为一种多相催化剂，在氧化脱硫方面表现出高效和常见的催化活性。

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《Crystal growth & design》 |2021年第2期|共7页
作者
Hong-Mei Gan; Chao Qin; Liang Zhao; Chunyi Sun; Xing-Long Wang; Zhong-Min Su;
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Institute of Functional Material Chemistry Local United Engineering Lab for Power Batteries Northeast Normal University;

Institute of Functional Material Chemistry Local United Engineering Lab for Power Batteries Northeast Normal University;

Institute of Functional Material Chemistry Local United Engineering Lab for Power Batteries Northeast Normal University;

Institute of Functional Material Chemistry Local United Engineering Lab for Power Batteries Northeast Normal University;

Institute of Functional Material Chemistry Local United Engineering Lab for Power Batteries Northeast Normal University;

Institute of Functional Material Chemistry Local United Engineering Lab for Power Batteries Northeast Normal University;

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正文语种 eng
中图分类晶体学;
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Self-Assembled Polyoxometalate-Based Metal-Organic Polyhedra as an Effective Heterogeneous Catalyst for Oxidation of Sulfide

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