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A Life in Electrochemistry

机译：电化学生活

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摘要

To tread a newly opened furrow, to feel complete freedom of action, and to see on all sides new vistas opening for research, brings with it a joy that only those who have had the raw pleasure of original research are fully in a position to grasp. Work in electrochemistry over more than two centuries has had a truly revolutionary, and sometimes underappreciated, role in science and technology. The first period (Volta period) introduced the first reliable source of electricity in an area that remains important in searches for new batteries for devices, propulsion, and grid storage. The second (Davy period) showed how many new elements and compounds, not previously available in chemistry, could be prepared using electricity (e.g., fluorine). The third (Nernst period) connected electrochemical measurements to thermodynamics and solution physical chemistry. The fourth (Heyrovsky period) introduced unique electroanalytical methods, especially for metal ions. The most recent period, which dates from approximately the middle of the twentieth century, connected the field to modern organic, inorganic, physical, and biochemistry and to theoretical concepts such as molecular orbital (MO) theory and mechanisms of outer and inner sphere electron-transfer reactions.
机译：踏出一条新的沟壑，感受完全的行动自由，并在各个方面看到新的研究视野，这带来了一种喜悦，即只有那些原始研究的原始乐趣者才能完全掌握。超过两个世纪以来，电化学工作在科学技术领域发挥了真正的革命性作用，有时甚至未被重视。第一个时期（伏特时期）在该地区寻找了第一个可靠的电力来源，这对于寻找用于设备，推进装置和电网存储的新电池仍然很重要。第二个（戴维时期）显示了可以使用电（例如氟）制备多少以前在化学中无法获得的新元素和化合物。第三个（能斯特期）将电化学测量与热力学和溶液物理化学联系起来。第四个（Heyrovsky时期）引入了独特的电分析方法，特别是对于金属离子。最近的时期大约是20世纪中叶，该领域将这一领域与现代有机，无机，物理和生物化学以及诸如分子轨道（MO）理论以及外层和内层电子的机理等理论概念联系起来。转移反应。

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