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Characteristics of coal tar residue treated with microwave-assisted hydrothermal treatment

机译:微波辅助水热处理治疗煤焦油残留的特征

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To achieve an efficient large-scale use of the coal tar residue (CTR), a microwave-assisted hydrothermal treatment was investigated to reduce its viscosity. The CTR was treated at various temperature with various liquid/solid (L/S) ratio by microwave-assisted hydrothermal. Then the thermogravimetry (TG) and the tube furnace combustion experiment were employed to study the combustion behavior and the NOx and SO2 emissions of the treated CTR. The results indicated that the microwave-assisted hydrothermal treatment with higher temperature and higher L/S ratio was beneficial to the viscosity reduction of the CTR. The TG results suggested that the treated CTR achieved a complete combustion only at a heating rate of 10 degrees C/min. Moreover, increasing the temperature and the L/S ratio reduced the comprehensive combustion characteristic index of the treated CTR. The results of combustion experiment indicated that the NOx emission of the treated CTR was less than 140 mg.m(-3), while the SO2 emission was less than 100 mg.m(-3). The microwave-assisted hydrothermal treatment is a promising method for the CTR, and the treated CTR can be applied as the fuel of circulating fluid beds (CFB) for industrial production.
机译:为了实现煤焦油残渣(CTR)的高效大规模利用,研究了微波辅助水热处理以降低其粘度。采用微波辅助水热法在不同温度、不同液固比(L/S)下对CTR进行处理。然后采用热重分析(TG)和管式炉燃烧实验研究了处理后CTR的燃烧行为以及NOx和SO2排放。结果表明,微波辅助水热处理,提高温度和L/S比,有利于CTR的降粘。TG结果表明,处理过的CTR仅在10℃/min的升温速率下实现完全燃烧。此外,提高温度和L/S比降低了处理过的CTR的综合燃烧特性指数。燃烧试验结果表明,处理后的CTR的NOx排放量小于140mg。m(-3),而SO2排放量小于100mg。m(-3)。微波辅助水热处理是一种很有前途的CTR处理方法,处理后的CTR可作为循环流化床(CFB)的燃料用于工业生产。

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