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High performance Li-ion capacitor fabricated with dual graphene-based materials

机译:高性能锂离子电容器,采用双石墨烯基材料制造

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摘要

Lithium-ion capacitors (LICs) are now drawing increasing attention because of their potential to overcome the current energy limitations of supercapacitors and power limitations of lithium-ion batteries. In this work, we designed LICs by combining an electric double-layer capacitor cathode and a lithium-ion battery anode. Both the cathode and anode are derived from graphene-modified phenolic resin with tunable porosity and microstructure. They exhibit high specific capacity, superior rate capability and good cycling stability. Benefiting from the graphene-enhanced electrode materials, the all graphene-based LICs demonstrate a high working voltage (4.2 V), high energy density of 142.9 Wh kg(-1), maximum power density of 12.1 kW kg(-1)with energy density of 50 Wh kg(-1), and long stable cycling performance (with similar to 88% capacity retention after 5000 cycles). Considering the high performance of the device, the cost-effective and facile preparation process of the active materials, this all graphene-based lithium-ion capacitor could have many promising applications in energy storage systems.
机译:锂离子电容器(LIC)因其克服超级电容器当前能量限制和锂离子电池功率限制的潜力而受到越来越多的关注。在这项工作中,我们通过结合双电层电容器阴极和锂离子电池阳极来设计锂离子电池。阴极和阳极均由石墨烯改性酚醛树脂制成,具有可调节的孔隙率和微观结构。它们具有高比容量、优异的倍率性能和良好的循环稳定性。得益于石墨烯增强电极材料,全石墨烯基锂离子电池表现出高工作电压(4.2 V)、高能量密度142.9 Wh-kg(-1)、最大功率密度12.1 kW-kg(-1),能量密度50 Wh-kg(-1),以及长期稳定的循环性能(5000次循环后的容量保持率接近88%)。考虑到该器件的高性能、低成本和易于制备的活性材料,这种全石墨烯基锂离子电容器在储能系统中有许多有前途的应用。

著录项

  • 来源
    《Nanotechnology》 |2021年第1期|共10页
  • 作者单位

    Luoyang Normal Univ Coll Chem &

    Chem Engn Key Lab Funct Oriented Porous Mat Luoyang 471934 Peoples R China;

    Nankai Univ Coll Chem Ctr Nanoscale Sci &

    Technol Tianjin 300071 Peoples R China;

    Nankai Univ Coll Chem Ctr Nanoscale Sci &

    Technol Tianjin 300071 Peoples R China;

    Luoyang Normal Univ Coll Chem &

    Chem Engn Key Lab Funct Oriented Porous Mat Luoyang 471934 Peoples R China;

    Nankai Univ Coll Chem Ctr Nanoscale Sci &

    Technol Tianjin 300071 Peoples R China;

    Nankai Univ Coll Chem Ctr Nanoscale Sci &

    Technol Tianjin 300071 Peoples R China;

    China Acad Engn Phys Inst Chem Mat Mianyang Sichuan Peoples R China;

    Nankai Univ Coll Chem Ctr Nanoscale Sci &

    Technol Tianjin 300071 Peoples R China;

  • 收录信息
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类 特种结构材料;
  • 关键词

    Li-ion capacitor; rate capability; cycling stability; dual graphene-based materials; energy density;

    机译:锂离子电容器;速率能力;循环稳定性;双石墨烯基材料;能量密度;

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