Catalytic transfer hydrogenation of furfural to furfuryl alcohol using easy-to-separate core-shell magnetic zirconium hydroxide

Hou Pan; Ma Mingwei; Zhang Peng; Cao Jingjie; Liu Hui; Xu Xingliang; Yue Huijuan; Tian Ge; Feng Shouhua

首页> 外文期刊>New Journal of Chemistry >Catalytic transfer hydrogenation of furfural to furfuryl alcohol using easy-to-separate core-shell magnetic zirconium hydroxide

【24h】

Catalytic transfer hydrogenation of furfural to furfuryl alcohol using easy-to-separate core-shell magnetic zirconium hydroxide

机译：易于单独的芯壳磁性锆碳氧化锆催化转移糠醛至糠醇富呋喃醇

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

A hollow core-shell magnetic zirconium hydroxide catalyst was synthesized and employed for the catalytic transfer hydrogenation (CTH) ofnumerous biomass-derived platform molecules (furfural and other carbonyl compounds). 93.9% conversion of furfural and 97.3% selectivity of furfuryl alcohol was achieved under mild reaction conditions (160 degrees C, 4 h, 0.1 g catalyst) with 2-propanol as the H-donor. After 7 times of reaction cycles, the catalyst retained excellent conversion (91.1%) and selectivity (97.8%) and no structural damage was found. Furthermore, a scale-up experiment was carried out, and the results proved that the catalyst has a prospect for industrial applications in the CTH reaction.

机译：合成了一种空心核壳磁性氢氧化锆催化剂，并将其用于多种生物质衍生平台分子（糠醛和其他羰基化合物）的催化转移氢化（CTH）。以2-丙醇为氢供体，在温和的反应条件下（160℃、4h、0.1g催化剂），糠醛的转化率为93.9%，糠醇的选择性为97.3%。经过7次反应循环后，催化剂保持了良好的转化率（91.1%）和选择性（97.8%），没有发现结构损伤。此外，还进行了放大实验，结果表明该催化剂在CTH反应中具有工业应用前景。

著录项

来源
《New Journal of Chemistry》 |2021年第5期|共8页
作者
Hou Pan; Ma Mingwei; Zhang Peng; Cao Jingjie; Liu Hui; Xu Xingliang; Yue Huijuan; Tian Ge; Feng Shouhua;
展开▼
作者单位

Jilin Univ Coll Chem State Key Lab Inorgan Synth &

Preparat Chem Changchun 130012 Peoples R China;

Jilin Univ Coll Chem State Key Lab Inorgan Synth &

Preparat Chem Changchun 130012 Peoples R China;

Jilin Univ Coll Chem State Key Lab Inorgan Synth &

Preparat Chem Changchun 130012 Peoples R China;

Jilin Univ Coll Chem State Key Lab Inorgan Synth &

Preparat Chem Changchun 130012 Peoples R China;

Jilin Univ Coll Chem State Key Lab Inorgan Synth &

Preparat Chem Changchun 130012 Peoples R China;

Shandong Agr Univ Coll Chem &

Mat Sci Tai An 271018 Shandong Peoples R China;

Jilin Univ Coll Chem State Key Lab Inorgan Synth &

Preparat Chem Changchun 130012 Peoples R China;

Jilin Univ Coll Chem State Key Lab Inorgan Synth &

Preparat Chem Changchun 130012 Peoples R China;

Jilin Univ Coll Chem State Key Lab Inorgan Synth &

Preparat Chem Changchun 130012 Peoples R China;

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类化学;
关键词

相似文献

外文文献
专利

1. Catalytic transfer hydrogenation of biomass-derived furfural to furfuryl alcohol with formic acid as hydrogen donor over CuCs-MCM catalyst [J] . Tao Wang, Juan Du, Yong Sun, 中国化学快报（英文版） . 2021,第003期
2. Performant Au hydrogenation catalyst cooperated with Cu-doped Al2O3 for selective conversion of furfural to furfuryl alcohol at ambient pressure [J] . Junjie Chen, Weixiao Sun, Yongxing Wang, 绿色能源与环境（英文） . 2021,第004期
3. Performant Au hydrogenation catalyst cooperated with Cu-doped Al_(2)O_(3)for selective conversion of furfural to furfuryl alcohol at ambient pressure [J] . Junjie Chen, Weixiao Sun, Yongxing Wang, 绿色能源与环境：英文版 . 2021,第004期
4. Hydrogenation of Furfural to Furfuryl Alcohol over Co-B Amorphous Catalysts Prepared by Chemical Reduction in Variable Media [J] . LI Hui, CHAI Wei-Mei, LUO Hong-Shan, 中国化学（英文版） . 2006,第012期
5. Furfural and Furfuryl alcohol Capacity Expands Unduly [J] . Tao Hailong 中国化工报导（英文版） . 2007,第001期
6. Catalytic transfer hydrogenation of furfural to furfuryl alcohol over a magnetic Fe3O4@C catalyst [J] . Li Feng, Jiang Shanshan, Huang Jin, New Journal of Chemistry . 2020,第2期

机译：在磁Fe3O4催化剂上催化转移糠醛在糠醇中糠醇
7. Magnetic Fe3O4 nanoparticles as easily separable catalysts for efficient catalytic transfer hydrogenation of biomass-derived furfural to furfuryl alcohol [J] . Ma Mingwei, Hou Pan, Zhang Peng, Applied Catalysis, A. General: An International Journal Devoted to Catalytic Science and Its Applications . 2020,第1期

机译：磁性Fe3O4纳米颗粒作为易分离的催化剂，用于生物质衍生的生物质衍生糠醛至糠醇的有效催化转移氢化
8. Catalytic Transfer Hydrogenation of Furfural into Furfuryl Alcohol over Magnetic gamma-Fe2O3@HAP Catalyst [J] . Wang Fan, Zhang Zehui ACS Sustainable Chemistry & Engineering . 2017,第1期

机译：在磁性γ-Fe2O3上催化转移糠醛糠醇中的糠醇 - HAP催化剂
9. Catalytic conversion of furfural to furfuryl alcohol over ruthenium based catalysts [C] . Sudiyarmanto Sudiyarmanto, Fauzan Aulia, Fauzul Adzim, International Symposium on Applied Chemistry . 2018

机译：用钌基催化剂催化转化糠醛在糠醇中的催化剂
10. Carbon-hydrogen bond functionalization via hydride transfer: Development of catalytic carbon-carbon bond forming reactions via intramolecular coupling of sp3 carbon hydrogen bonds and activated alkenes. [D] . McQuaid, Kevin Michael. 2009

机译：通过氢化物转移进行碳氢键官能化：通过sp3碳氢键与活化烯烃的分子内偶联，发展催化碳-碳键形成反应。
11. Microwave‐Assisted Selective Hydrogenation of Furfural to Furfuryl Alcohol Employing a Green and Noble Metal‐Free Copper Catalyst [O] . Pedro N. Romano, João M. A. R. de Almeida, Yuri Carvalho, -1

机译：微波辅助糠醛利用绿色无贵金属铜催化剂选择性氢化为糠醇
12. Furfuryl alcohol production by liquid phase catalytic transfer hydrogenation of furfural on alumina as Lewis acid catalyst [O] . Jiménez Gómez Carmen Pilar, Cecilia Buenestado Juan Antonio, Moreno Tost Ramón, 2017

机译：糠醛的液相催化转移加氢制备糠醛作为路易斯酸催化剂
13. Effects of Hydrogen on Magnetic Properties of Amorphous Zirconium Alloys [R] . Venturini, E. L., Bowman, R. C., Cantrell, J. S. 1984

机译：氢对非晶锆合金磁性能的影响

Catalytic transfer hydrogenation of furfural to furfuryl alcohol using easy-to-separate core-shell magnetic zirconium hydroxide

摘要

著录项

相似文献

相关主题

期刊订阅