...
首页> 外文期刊>Physica, B. Condensed Matter >Interfacial eg orbital reconstruction: Modulation of Metal-Insulator transitions of ultrathin NdNiO3 films by two-dimensional electronic gas
【24h】

Interfacial eg orbital reconstruction: Modulation of Metal-Insulator transitions of ultrathin NdNiO3 films by two-dimensional electronic gas

机译:界面EG轨道重建:通过二维电子气体调制超薄NDNIO3薄膜的金属 - 绝缘体转变

获取原文
获取原文并翻译 | 示例
           

摘要

Tunable metal-insulator transitions (MIT) of ultrathin NdNiO3 (NNO) film grown on the LaAlO3/SrTiO3 twodimensional electronic gas structures have been investigated by interfacial eg orbital reconstruction. Spectroscopy studies suggest that the polar catastrophe of the two-dimensional electronic gas results in Ni2+ to Ni3+ charge transfer of the NNO owing to the band-alignment condition. The orbital-hybridization of Ni 3d and O 2p can directly increase in-plane eg orbital occupancy, and the physical mechanism and modulation of the MIT can be clearly elucidated. This study not only provides new insight into the relationship between the electronic properties and orbital occupation, but it will also promote future application of epitaxial NNO thin films.
机译:用界面eg轨道重建方法研究了LaAlO3/SrTiO3二维电子气结构上生长的NdNiO3(NNO)超薄薄膜的可调谐金属-绝缘体跃迁(MIT)。光谱研究表明,由于能带排列条件,二维电子气的极性突变导致NNO的Ni2+到Ni3+电荷转移。Ni 3d和O 2p的轨道杂化可以直接增加面内eg轨道占有率,并且MIT的物理机制和调制可以清楚地阐明。这项研究不仅为研究电子性质与轨道占据之间的关系提供了新的见解,而且还将促进外延NNO薄膜的未来应用。

著录项

  • 来源
    《Physica, B. Condensed Matter》 |2021年第1期|共7页
  • 作者单位

    Hebei Univ Coll Qual &

    Tech Supervis Natl &

    Local Joint Engn Res Ctr Metrol Instrument Baoding 071002 Hebei Peoples R China;

    Hebei Univ Coll Qual &

    Tech Supervis Natl &

    Local Joint Engn Res Ctr Metrol Instrument Baoding 071002 Hebei Peoples R China;

    Hebei Univ Coll Phys Sci &

    Technol Hebei Key Lab Opt Elect Informat &

    Mat Baoding 071002 Hebei Peoples R China;

    Hebei Univ Coll Qual &

    Tech Supervis Natl &

    Local Joint Engn Res Ctr Metrol Instrument Baoding 071002 Hebei Peoples R China;

    Hebei Univ Coll Qual &

    Tech Supervis Natl &

    Local Joint Engn Res Ctr Metrol Instrument Baoding 071002 Hebei Peoples R China;

    Hebei Univ Coll Qual &

    Tech Supervis Natl &

    Local Joint Engn Res Ctr Metrol Instrument Baoding 071002 Hebei Peoples R China;

  • 收录信息
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类 物理学;
  • 关键词

    Orbital occupation; Metal-insulator transition; Charge transfer; X-ray linear dichroism;

    机译:轨道占用;金属-绝缘体过渡;费用转移;X射线线性二色性;

相似文献

  • 外文文献
  • 中文文献
  • 专利
获取原文

客服邮箱:kefu@zhangqiaokeyan.com

京公网安备:11010802029741号 ICP备案号:京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有
  • 客服微信

  • 服务号