M?ssbauer, Nuclear Forward Scattering, and Raman Spectroscopic Approaches in the Investigation of Bioinduced Transformations of Mixed-Valence Antimony Oxide

Nataliya  Chistyakova; Angelina  Antonova; Ivan  Elizarov; Pavel  Fabritchnyi; Mikhail  Afanasov; Mikhail  Korolenko; Maria  Gracheva; Diana  Pchelina; Ilya  Sergueev; Olaf  Leupold; René  Steinbrügge; Sergey  Gavrilov; Ilya  Kublanov; Vyacheslav  Rusakov

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M?ssbauer, Nuclear Forward Scattering, and Raman Spectroscopic Approaches in the Investigation of Bioinduced Transformations of Mixed-Valence Antimony Oxide

机译：M？Ssbauer，核前进散射和拉曼光谱方法研究了混合价锑氧化物的生物诱导转化

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M?ssbauer spectroscopy, nuclear forward scattering, and Raman spectroscopy were applied to study redox transformations of the synthesized mixed-valence (III/V) antimony oxide. The transformations were induced by a culture of a hyperthermophilic archaeon of the genus Pyrobaculum . The applied methods allowed us to reveal the minor decrease of ca. 11.0 ± 1.2% of the antimony(V) content of the mixed-valence oxide with the concomitant increase of antimony(III). The method sensitivities for the quantitative assessment of the Sb(III/V) ratio have been considered.

机译：M应用穆斯堡尔谱、核前向散射和拉曼光谱研究了合成的混合价（III/V）氧化锑的氧化还原转变。这些转化是由焦杆菌属超嗜热古生菌的培养诱导的。应用的方法使我们能够揭示混合价氧化物中锑（V）含量的约11.0±1.2%的轻微下降，同时锑（III）的增加。考虑了定量评估Sb（III/V）比值的方法灵敏度。

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《The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory》 |2021年第1期|共7页
作者
Nataliya Chistyakova; Angelina Antonova; Ivan Elizarov; Pavel Fabritchnyi; Mikhail Afanasov; Mikhail Korolenko; Maria Gracheva; Diana Pchelina; Ilya Sergueev; Olaf Leupold; René Steinbrügge; Sergey Gavrilov; Ilya Kublanov; Vyacheslav Rusakov;
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作者单位

Department of Physics Lomonosov Moscow State University;

Department of Physics Lomonosov Moscow State University;

Winogradsky Institute of Microbiology Federal Research Center of Biotechnology Russian Academy of Sciences;

Department of Chemistry Lomonosov Moscow State University;

Department of Chemistry Lomonosov Moscow State University;

Department of Chemistry Lomonosov Moscow State University;

Department of Physics Lomonosov Moscow State University;

Department of Physics Lomonosov Moscow State University;

Deutsches Elektronen-Synchrotron DESY;

Deutsches Elektronen-Synchrotron DESY;

Deutsches Elektronen-Synchrotron DESY;

Winogradsky Institute of Microbiology Federal Research Center of Biotechnology Russian Academy of Sciences;

Winogradsky Institute of Microbiology Federal Research Center of Biotechnology Russian Academy of Sciences;

Department of Physics Lomonosov Moscow State University;

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正文语种 eng
中图分类物理化学（理论化学）、化学物理学;
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M?ssbauer, Nuclear Forward Scattering, and Raman Spectroscopic Approaches in the Investigation of Bioinduced Transformations of Mixed-Valence Antimony Oxide

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