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首页> 外文期刊>Dalton transactions: An international journal of inorganic chemistry >The applications and prospects of hydrophobic metal-organic frameworks in catalysis
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The applications and prospects of hydrophobic metal-organic frameworks in catalysis

机译：催化作用疏水金属 - 有机骨架的应用及前景

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In recent years, large numbers of hydrophobic/superhydrophobic metal-organic frameworks (MOFs) have been developed. These hydrophobic MOFs not only retain rich structural variety, highly crystalline frameworks, and uniform micropores, but they also have lower affinity towards water and boosted hydrolytic stability. Until now, there were two main strategies to prepare hydrophobic MOFs, including a one-step method and post-synthesis modification (PSM). PSM was an often-used strategy for preparing hydrophobic MOFs. Hydrophobic MOFs showed unique advantages when used as catalysts for various categories of reactions. Herein, recent research advances relating to hydrophobic MOFs in the catalytic field are presented. The catalytic activities of hydrophobic MOFs and corresponding hydrophilic ones are also compared, and the superiority of hydrophobic MOFs or MOF materials as catalysts in 10 reactions is discussed. Finally, the advantages of hydrophobic MOFs as catalysts or auxiliary materials are summarized and promising future developments of hydrophobic MOFs are highlighted.
机译：近年来，大量疏水/超疏水金属有机骨架（MOF）被开发出来。这些疏水性MOF不仅保留了丰富的结构多样性、高度结晶的骨架和均匀的微孔，而且对水的亲和力较低，提高了水解稳定性。迄今为止，制备疏水性MOF主要有两种策略，包括一步法和合成后修饰法（PSM）。PSM是制备疏水性MOF的常用策略。疏水性MOF在用作各种反应的催化剂时显示出独特的优势。在此，介绍了疏水性MOF在催化领域的最新研究进展。比较了疏水性MOF和相应亲水性MOF的催化活性，讨论了疏水性MOF或MOF材料作为催化剂在10个反应中的优越性。最后，总结了疏水性MOF作为催化剂或辅助材料的优点，并展望了疏水性MOF的未来发展前景。

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