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Ion-conductive metal-organic frameworks

机译:离子导电金属 - 有机框架

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Metal-organic frameworks (MOFs) have emerged as a new class of ionic conductors because of their tuneable and highly ordered microporous structures. The ionic conduction of various ionic carriers, such as a proton (H+), hydroxide ion (OH-), lithium ion (Li+), sodium ion (Na+), and magnesium ion (Mg2+), in the pores of MOFs has been widely investigated over the past decade. Reports reveal that the porous or channel structures of MOFs are fundamentally suitable as ion-conducting pathways. There are clear differences in the basic designs of ion-conductive MOFs, i.e., the introduction of ionic carriers and construction of efficient ion-conducting pathways, depending on the ionic carriers. We summarize the examples and fundamental design of highly ion-conductive MOFs with various types of ionic carriers.
机译:金属有机骨架(MOF)是一类新型的离子导体,因为其具有可调的、高度有序的微孔结构。在过去的十年里,人们广泛研究了质子(H+)、氢氧化物离子(OH-)、锂离子(Li+)、钠离子(Na+)和镁离子(Mg2+)等各种离子载体在多功能有机化合物孔隙中的离子传导。报告显示,MOF的多孔或通道结构基本上适合作为离子传导途径。离子导电MOF的基本设计存在明显差异,即离子载体的引入和高效离子导电路径的构建取决于离子载体。我们总结了各种离子载体的高离子导电MOF的例子和基本设计。

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