pi-Hole spodium bonding in tri-coordinated Hg(ii) complexes

Gomila Rosa M.; Bauza Antonio; Mooibroek Tiddo J.; Frontera Antonio

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pi-Hole spodium bonding in tri-coordinated Hg(ii) complexes

机译：三孔锻炼在三（II）复合物中粘合

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The important role of pi-hole spodium bonding in tri-coordinated planar Hg(ii) complexes is highlighted in this feature article. Selected examples of Hg(ii)X-3 structures (X = any atom) illustrate that this noncovalent interaction is relevant as a structural guiding force in crystal structures. For some examples, the interactions have been characterized using the quantum theory of "atoms in molecules" and the noncovalent interaction plot index. Finally, an analysis of the Cambridge structural database revealed that the HgX3 structures are predominantly T-shaped and that they are directional pi-hole donors for electron rich atoms.

机译：这篇专题文章强调了π-空穴-锂键在三配位平面Hg（ii）配合物中的重要作用。Hg（ii）X-3结构（X=任何原子）的选定示例说明，这种非共价相互作用与晶体结构中的结构导向力有关。例如，利用“分子中原子”的量子理论和非共价相互作用图指数对相互作用进行了表征。最后，对剑桥结构数据库的分析表明，HgX3结构主要为T形，它们是富电子原子的定向π空穴供体。

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《Dalton transactions: An international journal of inorganic chemistry》 |2021年第22期|共9页
作者
Gomila Rosa M.; Bauza Antonio; Mooibroek Tiddo J.; Frontera Antonio;
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Univ Illes Balears Serv Cient Tecn Crta Valldemossa Km 7-5 Palma De Mallorca 07122 Baleares Spain;

Univ Illes Balears Dept Chem Crta Valldemossa Km 7-5 Palma De Mallorca 07122 Baleares Spain;

Univ Amsterdam Vant Hoff Inst Mol Sci Sci Pk A 904 E1-26 NL-1098 XH Amsterdam Netherlands;

Univ Illes Balears Dept Chem Crta Valldemossa Km 7-5 Palma De Mallorca 07122 Baleares Spain;

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正文语种 eng
中图分类化学;无机化学;
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pi-Hole spodium bonding in tri-coordinated Hg(ii) complexes

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