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首页> 外文期刊>Dalton transactions: An international journal of inorganic chemistry >2-D spin crossover materials at the nanometric scale: the effects of the size-reduction on the magnetic properties
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2-D spin crossover materials at the nanometric scale: the effects of the size-reduction on the magnetic properties

机译：纳米尺度的2-D旋转交叉材料：尺寸减小对磁性的影响

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摘要

Spin Crossover (SCO) particles at the nanometric scale provide an alternative point of view and a new perspective concerning the development of a new generation of spintronic, electronic, photonic and mechanical devices. The coexistence of the SCO phenomenon with the accompanying hysteresis loop enhances the functionality of future devices for storing and processing information. Despite all promising facts, the SCO phenomena are greatly affected by cooperativity issues resulting in a direct relation between the decrease of the size of nanopatricle and the overall decrease of cooperativity towards more gradual spin transitions. This minireview aims to summarise the synthetic techniques for the synthesis of 2-D Fe-II SCO particles at the nanometric scale, an underexplored area of research, highlighting the effects of the size-reduction on the magnetic properties of the corresponding nanoparticles and hopefuly showcasing the importance of studying in the context of 2D limit the SCO phenomena.
机译：纳米尺度的自旋交叉（SCO）粒子为开发新一代自旋电子学、电子、光子和机械设备提供了另一种观点和新视角。SCO现象与伴随的磁滞回线共存，增强了未来设备存储和处理信息的功能。尽管存在所有有希望的事实，但SCO现象受到合作性问题的极大影响，这导致纳米颗粒尺寸的减小与合作性朝着更渐进的自旋转变的总体降低之间存在直接关系。本小综述旨在总结纳米尺度下合成2-D Fe II SCO粒子的合成技术，这是一个尚未得到充分探索的研究领域，强调了尺寸减小对相应纳米颗粒磁性的影响，并有望展示在二维SCO现象背景下研究的重要性。

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