Tris-(2-pyridylmethyl)amine-ligated Cu(II) 1,3-diketonate complexes: anaerobic retro-Claisen and dehalogenation reactivity of 2-chloro-1,3-diketonate derivatives

Elsberg Josiah G. D.; Anderson Stephen N.; Tierney David L.; Reinheimer Eric W.; Berreau Lisa M.

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Tris-(2-pyridylmethyl)amine-ligated Cu(II) 1,3-diketonate complexes: anaerobic retro-Claisen and dehalogenation reactivity of 2-chloro-1,3-diketonate derivatives

机译：三 - （2-吡啶基甲基）胺连接Cu（II）1,3-二酮酸盐复合物：厌氧复合物和2-氯-1,3-二酮衍生物的脱卤反应性

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We report synthetic, structural and reactivity investigations of tris-(2-pyridylmethyl)amine (TPA)-ligated Cu(II) 1,3-diketonate complexes. These complexes exhibit anaerobic retro-Claisen type C-C bond cleavage reactivity which exceeds that found in analogs supported by chelate ligands with fewer and/or weaker pyridyl interactions.

机译：我们报道了三-（2-吡啶甲基）胺（TPA）配体铜（II）1,3-二酮酸盐配合物的合成、结构和反应性研究。这些配合物表现出厌氧逆克莱森型C-C键断裂反应性，超过了由吡啶基相互作用较少和/或较弱的螯合配体支撑的类似物中的反应性。

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《Dalton transactions: An international journal of inorganic chemistry》 |2021年第5期|共9页
作者
Elsberg Josiah G. D.; Anderson Stephen N.; Tierney David L.; Reinheimer Eric W.; Berreau Lisa M.;
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作者单位

Utah State Univ Dept Chem &

Biochem 0300 Old Main Hill Logan UT 84322 USA;

Utah State Univ Dept Chem &

Biochem 0300 Old Main Hill Logan UT 84322 USA;

Miami Univ Dept Chem &

Biochem Oxford OH 45056 USA;

Rigaku Amer Corp 9009 New Trails Dr The Woodlands TX 77381 USA;

Utah State Univ Dept Chem &

Biochem 0300 Old Main Hill Logan UT 84322 USA;

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正文语种 eng
中图分类化学;无机化学;
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Tris-(2-pyridylmethyl)amine-ligated Cu(II) 1,3-diketonate complexes: anaerobic retro-Claisen and dehalogenation reactivity of 2-chloro-1,3-diketonate derivatives

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