Unique catalytic properties of Ni–Ir alloy for the hydrogenation of N-heteroaromatics

Bai Jia-qi; Tamura Masazumi; Nakagawa YoshinaoTomishige Keiichi

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Unique catalytic properties of Ni–Ir alloy for the hydrogenation of N-heteroaromatics

机译：Ni-ir合金的独特催化特性，用于N杂瘤化的氢化

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SiO2-supported Ni–Ir alloy acted as an effective heterogeneous catalyst for the hydrogenation of pyridine to piperidine, providing about 16-fold higher activity based on the catalyst amount than monometallic Ir and Ni catalysts. The catalyst was applicable to the hydrogenation of pyridines and quinolines, giving corresponding piperidines and 1,2,3,4-tetrahydroquinolines in high selectivities (up to >99.9%).

机译：SIO2支持的Ni-IR合金充当吡啶氢化为哌啶的有效异质催化剂，基于催化剂量比单金属IR和Ni催化剂提供了约16倍的活性。该催化剂适用于吡啶和喹啉的氢化，可提供相应的哌啶和1,2,3,4-四氢喹啉的高选择性（高达99.9％）。

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来源
《Catalysis science & technology》 |2022年第8期|2420-2425|共6页
作者
Bai Jia-qi; Tamura Masazumi; Nakagawa YoshinaoTomishige Keiichi;
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作者单位

Tohoku University;

Osaka City University;

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原文格式 PDF
正文语种英语
中图分类汉语教学;
关键词
Hydrogenation; Pyridines; Catalystsheterogeneous catalystQuinolinesMETAL ALLOYCatalysisPiperidinespiperidineNickel;

机译：氢化;吡啶;催化丝菌催化丝氨酸金属合金磷脂piperidinespiperidinespiperidinicinenickel;

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Unique catalytic properties of Ni–Ir alloy for the hydrogenation of N-heteroaromatics

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