...
首页> 外文期刊>Catalysis science & technology >Molybdenum blue nano-rings: an effective catalyst for the partial oxidation of cyclohexane
【24h】

Molybdenum blue nano-rings: an effective catalyst for the partial oxidation of cyclohexane

机译:钼蓝纳米环:环己烷的部分氧化的有效催化剂

获取原文
获取原文并翻译 | 示例
           

摘要

Molybdenum blue (MB), a multivalent molybdenum oxide with a nano-ring morphology is well-known in analytical chemistry but, to date it has been largely ignored in other applications. In the present work, MB has been characterized by STEM-HAADF imaging for the first time, showing the nano-ring morphology of this complex molybdenum oxide and the ordered super-molecular framework crystals that can result from the self-assembly of these MB nano-ring units. The potential of MB as an oxidation catalyst has also been investigated, where it is shown to have excellent catalytic activity and stability in the selective oxidation of cyclohexane to cyclohexanol and cyclohexanone which are important intermediates in the production of nylon.
机译:钼蓝(MB)是一种具有纳米形态的多价氧化钼,在分析化学中是众所周知的,但迄今为止,在其他应用中,它在很大程度上被忽略了。 在目前的工作中,MB首次以STEM-HAADF成像为特征,显示了这种复杂的氧化钼和有序的超分子框架晶体的纳米环形态,这些晶体可能是由这些MB纳米的自组装产生的 - 环单元。 还研究了MB作为氧化催化剂的潜力,在该催化剂中,在其选择性氧化环己烷对环己醇和环己烯酮的选择性氧化中具有出色的催化活性和稳定性,这在尼龙的产生中是重要的中间体。

著录项

相似文献

  • 外文文献
  • 中文文献
获取原文

客服邮箱:kefu@zhangqiaokeyan.com

京公网安备:11010802029741号 ICP备案号:京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有
  • 客服微信

  • 服务号