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Structural design of TiO2-based photocatalyst for H-2 production and degradation applications

机译:用于H-2生产和降解应用的基于TIO2的光催化剂的结构设计

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摘要

TiO2-based photocatalysts, being inexpensive and abundant, in conjunction with having high photostability and environmentally friendly characteristics, are the most extensively studied photocatalytic material for hydrogen production and pollutant degradation. However, its existing issues, such as wide bandgap, high overpotential and rapid recombination of photogenerated carriers limit its photocatalytic properties. The opportunities for structural development of a TiO2 nanomaterial towards highly efficient and pragmatic photocatalysis applications are evidently plentiful. Hence, in this review, we will look into critical structural engineering strategies that give favorable physicochemical properties such as improved light absorption, photostability, charge-carrier dynamics, increase surface area etc. that benefit photocatalysis functionalities. Amongst the various structural engineering options, we will be covering the most prevalent and elegant core-shell and hierarchical structural designs, which rationally combine the advantages of structural manipulation and multi-material composition engineering. This review aims to provide a comprehensive and contemporary overview, as well as a guide of the development of new generation TiO2 based photocatalysts via structural design for improved solar energy conversion technologies.
机译:基于TIO2的光催化剂廉价且丰富,结合具有高光稳定性和环境友好的特性,是用于氢生产和污染物降解的最广泛研究的光催化材料。然而,其现有问题,例如宽带隙,光生载体的高电势和快速重组限制了其光催化特性。 TIO2纳米材料对高效和务实的光催化应用的结构发展的机会显然很丰富。因此,在这篇综述中,我们将研究关键的结构工程策略,这些策略具有良好的物理化学特性,例如改善的光吸收,光稳定性,电荷载体动力学,增加表面积等,从而使光催化功能受益。在各种结构工程选择中,我们将涵盖最普遍,优雅的核心和等级结构设计,从理性地结合结构操纵和多物质组成工程的优势。这篇综述旨在提供全面的现代概述,并通过结构设计为改进的太阳能转换技术开发基于新一代TiO2的光催化剂的指南。

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