Selective NaOH-catalysed hydration of aromatic nitriles to amides

Schmid Thibault E.; Gomez-Herrera Alberto; Songis OlivierSneddon DeborahRevolte AntoineNahra FadyCazin Catherine S. J.

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Selective NaOH-catalysed hydration of aromatic nitriles to amides

机译：选择性的NaOH芳族芳族水合与酰胺的水合

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摘要

The selective synthesis of aromatic and heteroaromatic amides through base-catalysed hydration of nitriles was achieved using inexpensive and commercially available NaOH as the only catalyst. A wide range of nitriles was selectively converted to their corresponding amides. Kinetic studies show that the double hydration of nitriles towards undesirable carboxylic acids is negligible under our reaction conditions.

机译：使用廉价和市售的NaOH作为唯一的催化剂，通过硝化液的碱基水合通过基础催化剂的水合来选择性合成芳香族和异源酰胺。将广泛的硝酸盐选择性地转换为相应的酰胺。动力学研究表明，在我们的反应条件下，硝酸盐对不良羧酸的双重水合可以忽略不计。

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来源
《Catalysis science & technology》 |2015年第5期|2865-2868|共4页
作者
Schmid Thibault E.; Gomez-Herrera Alberto; Songis OlivierSneddon DeborahRevolte AntoineNahra FadyCazin Catherine S. J.;
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作者单位

Univ St Andrews, Sch Chem, EaStCHEM, St Andrews KY16 9ST, Fife, Scotland;

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原文格式 PDF
正文语种英语
中图分类汉语教学;
关键词
Hydration; Nitriles; amides;

机译：水合;硝酸盐;酰胺;

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1. Aromatic International's Web Site Aromatic International LLC [J] . Perfumeramp, Flavorist group Perfumer & Flavorist . 2004,第5期

机译：Aromatic International的网站Aromatic International LLC
2. Neural activity in the periaqueductal gray and other specific subcortical structures is enhanced when a selective serotonin reuptake inhibitor selectively prevents seizure-induced sudden death in the DBA/1 mouse model of sudden unexpected death in epilepsy [J] . Kommajosyula Srinivasa P., Faingold Carl L. Epilepsia: Journal of the International League against Epilepsy . 2019,第6期

机译：Neural activity in the periaqueductal gray and other specific subcortical structures is enhanced when a selective serotonin reuptake inhibitor selectively prevents seizure-induced sudden death in the DBA/1 mouse model of sudden unexpected death in epilepsy
3. VCD Robustness of the Amide-I and Amide-II Vibrational Modes of Small Peptide Models [J] . Gobi Sandor, Magyarfalvi Gabor, Tarczay Gyoergy Chirality: The pharmacological, biological, and chemical consequences of molecular asymmetry . 2015,第9期

机译：VCD小肽模型的Amide-I和Amide-II振动模式的鲁棒性
4. Complete Hydroclechlorination of Chioro-Aromatics Catalyzed by Pd/TiO_2 with H_2 [C] . Ichiro Yamanaka, Koji Nishikawa, Sakae Takenaka, Tokyo Conference on Advanced Catalytic Science and Technology . 2003

机译：用H_2催化PD / TiO_2催化的Chioro-aromatics的完全氢化氢氯化物
5. Enabling the Selective Conversion of Biomass-Derived Oxygenates to C4-C5 Dienes =使生物质衍生的含氧化合物选择性转化为C4-C5二烯 [D] . Kumar, Gaurav. 2021

机译：Enabling the Selective Conversion of Biomass-Derived Oxygenates to C4-C5 Dienes =使生物质衍生的含氧化合物选择性转化为C4-C5二烯
6. Exendin(9-39)amide is an antagonist of glucagon-like peptide-1(7-36)amide in humans. [O] . J Schirra, K Sturm, P Leicht, 1998

机译：Exendin（9-39）amide是人体中胰高血糖素样肽-1（7-36）amide的拮抗剂。
7. 4-N,N-Dimethylaminopyridine Promoted Selective Oxidation of Methyl Aromatics with Molecular Oxygen [O] . Zhang, Zhan, Gao, Jin, Wang, Feng, 2012

机译：4-N,N-Dimethylaminopyridine promoted selective Oxidation of methyl aromatics with molecular Oxygen
8. Blends of Poly(Enamino Nitrile) [R] . Moore, J. A., Kim, J. H. 1992

机译：poly（Enamino Nitrile）的混合物

Selective NaOH-catalysed hydration of aromatic nitriles to amides

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