The role of reversibility in the enantioselective conjugate addition of a,a-disubstituted aldehydes to nitro-olefins catalyzed by primary amine thioureast

Yining Ji; Donna G. Blackmond

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The role of reversibility in the enantioselective conjugate addition of a,a-disubstituted aldehydes to nitro-olefins catalyzed by primary amine thioureast

机译：可逆性在对映选择性共轭物中的作用，将A二取代的醛添加到硝基烯烃中，由原代胺催化

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Kinetic and spectroscopic studies probing the conjugate addition of 2-phenylpropanal to nitro-olefins catalyzed by two different primary amine thiourea catalysts reveal the nature of the catalyst resting state and demonstrate that reversibility of the reaction is implicated in cases of low enantio-and diastereoselectivity.

机译：动力学和光谱研究探测了由两种不同的原发性胺硫脲催化剂催化的硝基烯烃结合添加的2-苯基丙烯剂，这揭示了催化剂静止状态的性质，并证明了该反应的可逆性在低乙酸和腹膜内二酰粘粘膜;

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《Catalysis science & technology》 |2014年第10期|3505-3509|共5页
作者
Yining Ji; Donna G. Blackmond;
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作者单位

Department of Chemistry, The Scripps Research Institute, Lajolla, CA 92037, USA;

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正文语种英语
中图分类汉语教学;
关键词
aldehydes; resting state; ReversibilityConjugatesCatalystshydratropic aldehydeKineticsAmines;

机译：醛;静止状态;可逆性ConconjugatesCatalystshydratropic醛;

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The role of reversibility in the enantioselective conjugate addition of a,a-disubstituted aldehydes to nitro-olefins catalyzed by primary amine thioureast

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