Merging metal-organic framework catalysis with organocatalysis: A thiourea functionalized heterogeneous catalyst at the nanoscale

Yi Luan; Nannan Zheng; Yue Qi

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Merging metal-organic framework catalysis with organocatalysis: A thiourea functionalized heterogeneous catalyst at the nanoscale

机译：合并金属有机框架与有机催化的催化：纳米级的硫脲功能化异质催化剂

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摘要

A new thiourea-containing metal-organic framework (MOF) catalyst was synthesized. It overcomes recycling, self-aggregation and solvation issues that exist in homogeneous thiourea catalysts. Nanomorphology was introduced to increase the dispersion of the solid catalyst in solvent. Acetalization and Morita-Baylis-Hillman reactions were catalyzed using the new thiourea MOF catalyst.

机译：合成了一种新的含硫脲金属有机框架（MOF）催化剂。它克服了同质硫脲催化剂中存在的回收，自我聚集和溶剂化问题。引入了纳米形态，以增加溶剂中固体催化剂的分散体。使用新的Thiourea MOF催化剂催化乙酰化和莫里塔 - 巴利斯 - 希尔曼反应。

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来源
《Catalysis science & technology》 |2014年第4期|925-929|共5页
作者
Yi Luan; Nannan Zheng; Yue Qi;
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作者单位

School of Materials Science and Engineering, University of Science and Technology Beijing, 30 Xueyuan Road, Beijing 100083, PR China.;

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正文语种英语
中图分类汉语教学;
关键词
nanoscale; Catalysis; acetalizationBaylis Hillman reactionthioureasSOLID CATALYSTCatalystsheterogeneous catalystmergerFrameworks;

机译：纳米级;催化;乙酰化baylis hillman反应thioureassolid催化催化静脉静脉融合催化剂framegrameworks;

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Merging metal-organic framework catalysis with organocatalysis: A thiourea functionalized heterogeneous catalyst at the nanoscale

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