Direct allylation of alcohols using allyltrimethylsilane: a move towards an economical and ecological protocol for C-C bond formation

Atul Chaskar; Kaliyappan Murugan

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Direct allylation of alcohols using allyltrimethylsilane: a move towards an economical and ecological protocol for C-C bond formation

机译：使用烯丙基甲基硅烷直接烯丙基醇的直接烯丙基：朝着C-C键形成的经济和生态方案的转变

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摘要

The allylation of benzylic, allylic and propargylic alcohols by means of allyltrimethylsilane represents one of the most powerful, elegant and practical methods for the formation of carbon-carbon bonds in organic synthesis. This method has received considerable attention owing to the ability of allylated compounds to undergo further synthetic manipulations. The aim of this review is to summarise the recent trends and developments reported in the literature and to assist in the creation of novel methodologies.

机译：通过烯丙基甲基硅烷的苯基，烯丙基和丙烯酸醇的烯丙基化是有机合成中碳碳键形成的最强大，最优雅和实用的方法之一。由于酸化化合物经过进一步的合成操作的能力，该方法受到了相当大的关注。这篇综述的目的是总结文献中报道的最新趋势和发展，并协助创建新方法。

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来源
《Catalysis science & technology》 |2014年第7期|1852-1868|共17页
作者
Atul Chaskar; Kaliyappan Murugan;
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作者单位

National Taiwan University, Taipei, Taiwan;

Institute of Chemical Technology, Matunga, Mumbai 400019, India.;

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原文格式 PDF
正文语种英语
中图分类汉语教学;
关键词
practical methods; allylation; allyltrimethylsilaneBond formationMoving;

机译：实用方法;烯丙基化;烯丙基甲基硅烷基形成;

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1. Recent advances in the iron-catalyzed C-C bond formation via polar reactions of alcohols with carbon-centered nucleophiles [J] . SHANGXiaoJie, LIUZhongQuan 中国科学通报：英文版 . 2012,第19期
2. Direct Oxidative C-P Bond Formation of Indoles with Dialkyl Phosphites [O] . Wang Haolong, Li Xincheng, Wu Fan, 2012

机译：Direct Oxidative C-p Bond Formation of Indoles with Dialkyl phosphites

Direct allylation of alcohols using allyltrimethylsilane: a move towards an economical and ecological protocol for C-C bond formation

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