A convenient nickel-catalysed hydrosilylation of carbonyl derivatives

Jianxia Zheng; Christophe Darcel; Jean-Baptiste Sortais

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A convenient nickel-catalysed hydrosilylation of carbonyl derivatives

机译：羰基衍生物的方便镍催化氢硅烷基化

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摘要

Hydrosilylation of aldehydes and ketones catalysed by nickel acetate and tricyclohexylphosphine as the catalytic system was demonstrated using polymethylhydrosiloxane as a cheap reducing reagent.

机译：使用聚甲基氢氧烷作为廉价的还原试剂，证明了乙酸镍和三环己基膦将醛和酮的氢硅化化作为催化系统。

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来源
《Catalysis science & technology》 |2013年第1期|81-84|共4页
作者
Jianxia Zheng; Christophe Darcel; Jean-Baptiste Sortais;
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作者单位

Centre of Catalysis and Green Chemistry, Institut des Sciences Chimiques de Rennes, UMR 6226 CNRS-Universite Rennes 1, Team "Organometallics: Materials and Catalysis" Building IOC, Campus de Beaulieu, Ave General Leclerc, 35042 Rennes, France;

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正文语种英语
中图分类汉语教学;
关键词
polymethylhydrosiloxane; aldehydes; Ketoneshydrosilylationnickel acetatecarbonyl compoundsReducing Agents;

机译：聚甲基氢氧烷;醛;酮基硅烷基于乙酰基乙酰乙醇;

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1. Technetium and rhenium carbonyl complexes with 1,4-benzodiazepine derivatives: X-ray crystal structure [J] . Marchi A., Rossi R., Bertolasi V., Inorganica Chimica Acta . 1998,第2期

机译：1，和carbonyl羰基配合物与1,4-苯并二氮杂derivatives衍生物：X射线晶体结构
2. Electronic structures and spectral properties of rhenium(I) tricarbonyl diimine complexes with phosphine ligands: DFT/TDDFT theoretical investigations [J] . Zhao F., Wang J.-X., Liu W.-Q., Computational & theoretical chemistry . 2012,第null期

机译：carbonyl（I）三羰基二亚胺carbonyl与膦配体的电子结构和光谱性质：DFT / TDDFT理论研究
3. NUCLEOTIDES .50. AGLYCONE PROTECTION BY THE (2-DANSYLETHOXY)CARBONYL (=(2-([5-(DIMETHYLAMINO)NAPHTHALEN-1-YL]SULFONYL)ETHOXY)CARBONYL DNSEOC) GROUP - A NEW VARIATION IN OLIGODEOXYRIBONUCLEOTIDE SYNTHESIS [J] . Wagner T., Pfleiderer W. Helvetica chimica acta . 1997,第1期

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7. Short Intramolecular N–H⋯C(carbonyl) Interactions in Mixed-Ligand Molybdenum Hexacarbonyl Derivatives [O] . Matthew G. Budge, Kathleen J. Muir, Geoffrey P. McQuillan, 2011

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A convenient nickel-catalysed hydrosilylation of carbonyl derivatives

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