首页>
外文期刊>Catalysis science & technology
>Direct allylic animation of allylic alcohols with aromatic/aliphatic amines using Pd/TPPTS as an aqueous phase recyclable catalyst
【24h】
Direct allylic animation of allylic alcohols with aromatic/aliphatic amines using Pd/TPPTS as an aqueous phase recyclable catalyst
Direct activation of C-O bonds in cinnamyl/allyl alcohols with aromatic/aliphatic amines in aqueous medium using a water soluble Pd(OAc)2/TPPTS catalyst has been reported. The catalyst is highly efficient, chemoselective, simple, atom economical, greener and reusable up to eight consecutive cycles without aid of any co-catalyst. The protocol is applicable to a wide range of hindered and functionalized aromatic/aliphatic amines with excellent yield of the corresponding allyl amines.
展开▼
