A straightforward zinc-catalysed reduction of sulfoxides to sulfides

Stephan Enthaler

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A straightforward zinc-catalysed reduction of sulfoxides to sulfides

机译：直接的锌催化硫氧化物还原为硫化物

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摘要

In the present study, the zinc-catalysed reduction of a variety of sulfoxides with silanes as reductant to the corresponding sulfide has been examined in detail. With the straightforward and commercially available zinc(II) triflate as pre-catalyst, excellent yields and chemoselectivities were feasible. After studying the reaction conditions and the scope and limitations several attempts were undertaken to shed light on the reaction mechanism.

机译：在本研究中，已详细研究了各种用硅烷为相应硫化物还原剂的多种亚硫氧化物的锌催化的还原。以直接和市售的锌（II）为催化剂，优异的产率和化学选择性是可行的。在研究了反应条件以及范围和局限性后，进行了几次尝试，以阐明反应机制。

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来源
《Catalysis science & technology》 |2011年第1期|104-110|共7页
作者
Stephan Enthaler;
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作者单位

Technische Universitat Berlin, Department of Chemistry, Cluster of Excellence "Unifying Concepts in Catalysis", Strasse des 17. Juni 135, D-10623 Berlin, Germany;

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原文格式 PDF
正文语种英语
中图分类汉语教学;
关键词
Sulfoxides; silanes; reductionCHEMOSELECTIVITYReaction Mechanisms;

机译：亚氧化物;硅烷;还原的脱氧性反应机制;

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A straightforward zinc-catalysed reduction of sulfoxides to sulfides

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