Selective hydrogenation of functionalized nltroarenes under mild conditions

Valerica Pandarus; Rosaria Ciriminna; Francois Beland

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Selective hydrogenation of functionalized nltroarenes under mild conditions

机译：在轻度条件下功能化的NltroRarenes的选择性氢化

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摘要

Functionalized anilines are selectively synthesized from the corresponding nitroarenes by simple heterogeneous catalytic hydrogenation carried out under mild conditions over a very low amount (0.5 mol%) of a new sol-gel entrapped Pd(0) catalyst. Only halo-nitroarenes could not be selectively converted. The catalyst is leach-proof and can be reused in many consecutive reaction cycles.

机译：功能化的苯胺是通过在轻度条件下在非常低的量（0.5 mol％）的新溶胶凝胶（0）催化的PD（0）催化剂中在轻度条件下进行的简单异质催化氢化选择性合成的。只能选择性地转换后，只能选择性转换。该催化剂是防浸出的，可以在许多连续的反应周期中重复使用。

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来源
《Catalysis science & technology》 |2011年第9期|1616-1623|共8页
作者
Valerica Pandarus; Rosaria Ciriminna; Francois Beland;
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作者单位

SiliCycle Inc., 2500, Parc-Technologique Blvd. Quebec City. Quebec, Canada G1P 4S6.;

Istituto per lo Studio dei Materiali Nanostrutturati, CNR, via U. La Malfa 153, 90146 Palermo, Italy.;

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原文格式 PDF
正文语种英语
中图分类汉语教学;
关键词
Catalysts; Hydrogenation; Nitroarene CompoundSol-gels;

机译：催化剂;氢化;硝化化合物 - 凝胶;

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Selective hydrogenation of functionalized nltroarenes under mild conditions

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