Free radical and RAFT polymerization of vinyl esters in metal-organic-frameworks

Hwang Jongkook; Lee Hui-Chun; Antonietti MarkusSchmidt Bernhard V. K. J.

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Free radical and RAFT polymerization of vinyl esters in metal-organic-frameworks

机译：自由基和筏乙烯的聚合酯在metal-organic-frameworks

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Free radical and RAFT polymerization of vinyl esters with different molecular dimensions are conducted in the nanochannels of metal-organic-frameworks (MOFs). The combination of MOFs with the RAFT technique enables the synthesis of highly isotactic poly(vinyl ester)s with a controlled molecular weight and narrow molecular weight distribution, and stereocontrolled isotactic-block-atactic vinyl ester block copolymers.

机译：自由基和筏乙烯的聚合酯与不同的分子尺寸纳米通道中进行metal-organic-frameworks (mof)。财政部的大量技术支持高度等规聚(乙烯基酯)的合成控制分子量和狭窄的分子量分布stereocontrolled isotactic-block-atactic乙烯基酯嵌段共聚物。

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来源
《Polymer chemistry》 |2017年第40期|6204-6208|共5页
作者
Hwang Jongkook; Lee Hui-Chun; Antonietti MarkusSchmidt Bernhard V. K. J.;
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作者单位

Max Planck Inst Colloids & Interfaces, Dept Colloid Chem, Muhlenberg 1, D-14476 Potsdam, Germany;

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正文语种英语
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关键词
VINYL ESTER; Molecular weight distribution; Molecular weightsmetal organic frameworkFree radicalsRAFTPolymerization;

机译：乙烯基酯;分子量分布;weightsmetal有机分子frameworkFree radicalsRAFTPolymerization;

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Free radical and RAFT polymerization of vinyl esters in metal-organic-frameworks

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