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Sustainable nitrate production out of thin air: the photocatalytic oxidation of molecular nitrogen

机译:可持续的硝酸生产从稀薄的空气中:分子的光催化氧化氮

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摘要

Novel processes for the sustainable production of fertilizers are highly sought after to combat climate change. Herein, we demonstrate that by irradiating with strong UVA-light, TiO2 is able to photocatalytically oxidize molecular nitrogen in the gas phase under ambient conditions to NOx and nitrate. The reaction produces predominantly nitrogen dioxide with a high selectivity of up to 93% which could be captured afterwards to produce nitric acid or nitrates and used as sustainable (solar) fertilizer.
机译:小说的可持续生产流程肥料是高度追求战斗气候变化。辐射强UVA-light,二氧化钛保留氧化分子氮环境条件下气相中的氮氧化物和硝酸。二氧化氮的高选择性93%可以捕获之后生产硝酸或硝酸盐作为可持续(太阳能)肥料。

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