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Selectivity of the Lindlar catalyst in alkyne semi-hydrogenation: a direct liquid-phase adsorption study

机译:Lindlar催化剂的选择性炔semi-hydrogenation:直接液相吸附研究

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摘要

We study the alkyne semi-hydrogenation selectivity over Pd and Lindlar catalyst with liquid phase adsorption. The results indicate that there are strongly-adsorbing alkyne and alkene sites; alkenes react non-selectively over the alkene adsorption sites. DFT studies indicate that the non-selective sites are low-coordination Pd atoms in the nanoparticles.
机译:研究了炔semi-hydrogenation选择性在Pd和Lindlar与液相催化剂吸附。strongly-adsorbing炔烃和烯烃网站;在烯烃无可烯烃的反应吸附的网站。大众化的网站low-coordination Pd原子在纳米颗粒。

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