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Twin engineering of photocatalysts: a minireview

机译:两大工程的论文:一个小

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摘要

Twin crystals with highly ordered atomic arrangement can not only promote the transport of free charge carriers (electrons and holes) inside a single crystalline photocatalyst, but also limit the recombination of photoexcited charge carriers owing to their self-building electrostatic field. Hence, the investigations on twin-dependent photocatalytic performances of crystalline micro-/nanostructures have received much attention in recent years. However, there is still no specialized review article on twin engineering of photocatalysts so far. Herein, the existing twinned micro-/nanostructures, mainly including metal sulfides and metal oxides, are overviewed on the basis of the synthesis engineering, transmission electron microscopy (TEM) characterization and twin-dependent photocatalytic mechanism. Some challenging issues and future directions are also discussed. Expectantly, this minireview would serve as a theoretical guidance for people who are now focusing on twin crystals to design and synthesize novel photocatalysts.
机译:双胞胎与高度有序的原子晶体安排不仅可以促进运输自由载流子(电子和空穴)在里面一个水晶光催化剂,但也限制光激的电荷的复合航空公司由于他们的自身建设静电场。twin-dependent光催化性能晶体微/纳米结构已经收到近年来关注。还没有专门的评论文章的双胞胎工程的论文。主要是现有的成双成对的微/纳米结构金属硫化物和金属氧化物等综述的基础上合成工程,透射电子显微镜(TEM)表征和twin-dependent光催化机理。和未来的发展方向进行了讨论。期待地,这将成为一个小回顾理论指导的人了专注于设计和双晶体合成新的催化剂。

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