Simple reversible fixation of a magnetic catalyst in a continuous flow system: ultrafast reduction of nitroarenes and subsequent reductive amination using ammonia borane

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Simple reversible fixation of a magnetic catalyst in a continuous flow system: ultrafast reduction of nitroarenes and subsequent reductive amination using ammonia borane

机译：磁性催化剂的简单可逆固定在连续流系统:减少超速nitroarenes和随后的还原胺化作用使用氨硼烷

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Continuous reductive amination of aldehydes with nitroarenes over a Pd-Pt-Fe3O4 catalyst was performed. We used NH3BH3 as not only a hydrogen source for nitro reduction, but also a reductant for imine reduction. Secondary aromatic amines were obtained in the continuous flow reaction in good to excellent yields.

机译：连续的醛还原胺化在Pd-Pt-Fe3O4 nitroarenes催化剂执行。对硝基还原源,但也是一个还原剂亚胺还原。在连续流动反应了好优秀的收益率。

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《Catalysis science & technology》 |2020年第4期|944-949|共6页
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正文语种英语
中图分类汉语教学;
关键词
Continuous flow; aldehydes; BoranesAminationCatalystsContinuous flow systemsReducing Agents;

机译：连续流;醛类;BoranesAminationCatalyst;

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1. Convenient Asymmetric Borane Reduction of Ketones Catalyzed by Simple Amino Alcohols and Corresponding Amino Acids [J] . 中国化学快报（英文版） . 2002,第012期
2. Immobilized silver nanoparticles on silica gel as an efficient catalyst in nitroarene reduction [J] . Ali Reza Kiasat, Roya Mirzajani, Fakhri Ataeian, 中国化学快报：英文版 . 2010,第009期
3. Immobilized silver nanoparticles on silica gel as an efficient catalyst in nitroarene reduction [J] . Ali Reza Kiasat, Roya Mirzajani, Fakhri Ataeian, 中国化学快报（英文版） . 2010,第009期
4. Bifunctional Catalysis: Direct Reductive Amination of Aliphatic Ketones with an Iridium-Phosphate Catalyst [O] . Barbara Villa-Marcos, Chaoqun Li, Keith R. Mulholland, 2010

机译：Bifunctional Catalysis: Direct Reductive amination of aliphatic Ketones with an Iridium-phosphate Catalyst

Simple reversible fixation of a magnetic catalyst in a continuous flow system: ultrafast reduction of nitroarenes and subsequent reductive amination using ammonia borane

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