Regioselective aromatic O-demethylation with an artificial P450BM3 peroxygenase system

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Regioselective aromatic O-demethylation with an artificial P450BM3 peroxygenase system

机译：与一个特定选择的芳香O-demethylation人工P450BM3 peroxygenase系统

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Several simple single- and double-mutants of cytochrome P450BM3 enzymes enabled a highly regioselective O-demethylation of aromatic ethers with H2O2 with the assistance of a dual-functional small molecule (DFSM). The DFSM-facilitated P450BM3 peroxygenase system provides an alternative, simple approach for a key step in the bioconversion of lignin compared with reported NADPH-dependent P450 monooxygenases.

机译：几个简单的单,double-mutants细胞色素酶P450BM3启用了一个高度特定选择的O-demethylation芳香醚与过氧化氢的援助双功能小分子(传统)。DFSM-facilitated P450BM3 peroxygenase系统提供了一种替代方法,简单的方法相比,木质素的生物转化的关键一步与报道NADPH-dependent P450单氧酶。

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《Catalysis science & technology》 |2020年第5期|1219-1223|共5页
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正文语种英语
中图分类汉语教学;
关键词
hydrogen peroxide; Mutants; peroxygenasesimplicial approximationLigninbioconversionMonooxygenases;

机译：过氧化氢;突变;peroxygenasesimplicialapproximationLigninbioconversionMonooxygenases;

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Regioselective aromatic O-demethylation with an artificial P450BM3 peroxygenase system

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