Red phosphorus (RP) as an elemental semiconductor photocatalyst has been employed for photocatalytic hydrogen (H-2) production owing to its relatively narrow band gap (about 1.72 eV), excellent absorption features in the visible region, and favourable band structure. In this work, cobalt phosphide (Co2P) as a noble-metal-free co-catalyst was first loaded on two-dimensional microporous RP nanosheets by a one-step in situ hydrothermal method. The investigations demonstrated that the introduction of Co2P nanoparticles could facilitate the separation and migration of photogenerated charge carriers and provide numerous catalytic active sites for photocatalytic H-2 evolution. Besides, the stability of the composites was greatly enhanced by the formation of Co-P bonds between RP and Co2P. As expected, 2% Co2P/RP showed the highest H-2 evolution rate of 5997.5 mu mol h(-1) g(-1), which was 7.0 times and 2.4 times higher than those of pristine RP (857.6 mu mol g(-1) h(-1)) and Pt/RP (2469.9 mu mol g(-1) h(-1)), respectively. Moreover, the one-step solution-phase synthesis technology can be extensively applied for other transition-metal-phosphide-based photocatalysts.
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