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Construction of heterostructure based on hierarchical Bi2MoO6 and g-C3N4 with ease for impressive performance in photoelectrocatalytic water splitting and supercapacitor

机译:基于异质结构的建设层次Bi2MoO6和g-C3N4轻松在photoelectrocatalytic令人印象深刻的表现水分裂和超级电容器

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摘要

Herein, we report the synthesis of a nanohybrid material with hierarchical Bi2MoO6 and g-C3N4 by a solvothermal method. It shows impressive performance towards photoelectrocatalytic water splitting and supercapacitor applications due to the formation of type-II heterostructures, a higher surface area of 60.7 m(2)g(-1) (Bi2MoO6 - 44.0 m(2) g(-1)) and higher wettability. The formation of type-II heterostructures reduces the electron-hole recombination and boosts up the interfacial charge transfer in g-C3N4/Bi2MoO6, and the nanohybrid material (10 wt% g-C3N4) shows about 7- and 20-fold higher PEC efficiency than that of Bi2MoO6 and g-C3N4 under illumination (100 mW cm(-2) (AM 1.5G)). Besides, due to the combination of non-faradaic and faradaic processes, g-C3N4/Bi2MoO6 (5 wt% g-C3N4) exhibits a high specific capacity of 1628 C g(-1) at a current density of 2 A g(-1) in a three-electrode configuration. The symmetric supercapacitor delivers a maximum cell voltage of 1.8 V with a high energy density and a power density of 47 W h kg(-1) and 4500 W kg(-1), respectively, and also shows excellent electrochemical stability with 90% capacitance retention even after 10 000 cycles at a current density of 5 A g(-1).
机译:在此,我们报告的合成nanohybrid材料与分层Bi2MoO6 g-C3N4一个solvothermal方法。性能对photoelectrocatalytic水由于分裂和超级电容器应用程序二型异质结构的形成高表面积的60.7 g (1) (2) (Bi2MoO6 -44.0米(2)g(1))和更高的润湿性。形成ⅱ型异质结构减少了电子空穴复合,促进了在g-C3N4 / Bi2MoO6界面电荷转移,和nanohybrid材料(10 wt % g-C3N4)所示大约7岁和20倍压电效率高于Bi2MoO6和g-C3N4照明(100 mW厘米(2)(1.5 g))。non-faradaic和感应电流的流程,g-C3N4 / Bi2MoO6 (5 wt % g-C3N4)展品高的特定能力1628 C g (1)电流密度的2 g(1)在三电极配置。提供了最大的电池电压1.8 V高的能量密度和功率密度的47 W h公斤(1)和4500 W公斤(1),分别显示了良好的电化学稳定性电容保留即使000 90%周期的电流密度5 g(1)。

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