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Synergistic photocatalysis-Fenton reaction for selective conversion of methane to methanol at room temperature

机译:协同photocatalysis-Fenton反应甲烷,甲醇的选择性转换室温

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摘要

By combining the Fenton and photocatalytic reactions, the selective conversion of CH4 to CH3OH on TiO2 was significantly enhanced with solar light at room temperature. The yield and selectivity to methanol are up to 471 mu mol g(-1) h(-1) and 83%, respectively. The Fenton reaction favors the generation of radicals. Photocatalysis facilitates the closed cycle of catalysis and Fenton reagent restoration.
机译:通过结合芬顿,光催化反应,甲烷的选择性转换CH3OH在二氧化钛显著增强在室温下太阳能灯。甲醇选择性是471亩摩尔g (1) h(1)和83%,分别。反应有利于自由基的生成。光催化促进的闭合循环催化和芬顿试剂恢复。

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