Chemoenzymatic cascade for stilbene production from cinnamic acid catalyzed by ferulic acid decarboxylase and an artificial metathease

Mertens M. A. Stephanie; Sauer Daniel F.; Markel UlrichSchiffels JohannesOkuda JunSchwaneberg Ulrich

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Chemoenzymatic cascade for stilbene production from cinnamic acid catalyzed by ferulic acid decarboxylase and an artificial metathease

机译：对称二苯代乙烯生产糖类级联由阿魏酸催化肉桂酸脱羧酶和人造metathease

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We report the preparation of symmetrical stilbene derivatives in a two-step one-pot cascade reaction based on enzymatic decarboxylation of cinnamic acid followed by olefin cross metathesis. Embedment of the metathesis catalyst in a protein scaffold enabled the cascade reaction to symmetric stilbenes and furthermore very efficient removal of metal impurities (<1 ppm in product fraction).

机译：我们报告对称对称二苯代乙烯的制备在两步锅级联的衍生品基于酶脱酸反应肉桂酸烯烃交叉紧随其后置换作用。在蛋白质支架使级联对对称对称二苯代乙烯而且反应非常有效的去除的金属杂质(< 1在产品部分ppm)。

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来源
《Catalysis science & technology》 |2019年第20期|5572-5576|共5页
作者
Mertens M. A. Stephanie; Sauer Daniel F.; Markel UlrichSchiffels JohannesOkuda JunSchwaneberg Ulrich;
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作者单位

Rhein Westfal TH Aachen, Inst Biotechnol, Worringerweg 3, D-52074 Aachen, Germany;

Rhein Westfal TH Aachen, Inst Inorgan Chem, Landoltweg 1, D-52074 Aachen, Germany;

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正文语种英语
中图分类汉语教学;
关键词
Metathesis catalysts; stilbenes; Metathesiscinnamic acidimpurity removal;

机译：置换作用催化剂;对称二苯代乙烯;Metathesiscinnamicacidimpurity删除;

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1. RP-HPLC Determination and Pharmacokinetic Comparison of Cinnamic Acid in Rat Plasma After Administration of Di-Gu-Pi Decoction and Pure Cinnamic Acid [J] . 高等学校化学研究（英文版） . 2006,第001期
2. Inhibitory Effect of Ferulic Acid on Oxidation of L-DOPA Catalyzed by Mushroom Tyrosinase [J] . 龚盛昭, 程江, 杨卓如中国化学工程学报：英文版 . 2005,第006期
3. Tacrine-6-Ferulic Acid, a Novel Multifunctional Dimer Against Alzheimer's Disease, Prevents Oxidative Stress-Induced Neuronal Death Through Activating Nrf2/ARE/HO-1 Pathway in HT22 Cells [J] . HuangW.-Y., ChaoX.-J., OuyangY., CNS neuroscience & therapeutics . 2012,第11期

机译：Tacrine-6-Ferulic Acid，一种新型的针对阿尔茨海默氏病的多功能二聚体，通过激活HT22细胞中的Nrf2 / ARE / HO-1途径，预防氧化应激诱导的神经元死亡。
4. Homogeneous nanodiscs of native membranes formed by stilbene-maleic-acid copolymers [J] . Esmaili Mansoore, Brown Chanelle J., Shaykhutdinov RustemAcevedo-Morantes ClaudiaWang Yong LiangWille HolgerGandour Richard D.Turner S. RichardOverduin Michael Nanoscale . 2020,第32期

机译：齐次nanodiscs原生膜的形成由stilbene-maleic-acid共聚物
5. Bronsted-acid-catalyzed one-pot tandem annulation/[5+2]-cycloaddition ofo-propargyl alcohol benzaldehydes with alkynes: regioselective and stereoselective synthesis of dibenzo[a,f]azulen-12-ones [J] . Zhou Ni-Ni, Ning Si-Si, Li Lin-QiangZhang Jie-YunFan Ming-JinYang De-SuoZhu Hai-Tao Organic Chemistry Frontiers . 2020,第18期

机译：Bronsted-acid-catalyzed锅串联环状物/[5 + 2]环加成作用ofo-propargyl酒精与炔烃苯甲醛:特定选择的和立体选择合成
6. Tacrine‐6‐Ferulic Acid a Novel Multifunctional Dimer Against Alzheimers Disease Prevents Oxidative Stress‐Induced Neuronal Death Through Activating Nrf2/ARE/HO‐1 Pathway in HT22 Cells [O] . Wen‐Yong Huang, Xiao‐Juan Chao, Ying Ouyang, 2012

机译：Tacrine-6-Ferulic Acid一种新型的针对阿尔茨海默氏病的多功能二聚体可通过激活HT22细胞中的Nrf2 / ARE / HO-1途径防止氧化应激诱导的神经元死亡。
7. Sulfonic acid resin–catalyzed oxidation of aldehydes to carboxylic acids by hydrogen peroxide [O] . Xiaomei Yang, Si Tang, 芦天亮, 2013

机译：sulfonic acid resin–catalyzed oxidation of aldehydes to carboxylic acids by hydrogen peroxide

Chemoenzymatic cascade for stilbene production from cinnamic acid catalyzed by ferulic acid decarboxylase and an artificial metathease

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