Catalytic enhancement on Ti-Zr complex oxide particles for electrochemical hydrogenation of oxalic acid to produce an alcoholic compound by controlling electronic states and oxide structures

Yamauchi M.; Hata S.; Eguchi H.Kitano S.Fukushima T.Higashi M.Sadakiyo M.Kato K.

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Catalytic enhancement on Ti-Zr complex oxide particles for electrochemical hydrogenation of oxalic acid to produce an alcoholic compound by controlling electronic states and oxide structures

机译：催化氧化增强Ti-Zr复杂粒子的电化学加氢草酸生产一个酒鬼化合物控制电子态和氧化结构

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摘要

Ti1-xZrxO2 complex oxide particles with 0.02 <= x <= 0.1 show superior catalytic performances for the direct power storage into glycolic acid via electroreduction of oxalic acid. The atomic pair distribution function analysis of X-ray total scatterings suggested that structural periodicity is the key factor for the catalytic enhancement.

机译：0.02 < = x Ti1-xZrxO2复杂氧化物粒子< = 0.1显示优越的催化性能直接乙醇酸通过能量储存草酸电解还原。分布函数分析x射线计算结果表明,结构的周期性是催化增强的关键因素。

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来源
《Catalysis science & technology》 |2019年第23期|6561-6565|共5页
作者
Yamauchi M.; Hata S.; Eguchi H.Kitano S.Fukushima T.Higashi M.Sadakiyo M.Kato K.;
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作者单位

Kyushu Univ, Int Inst Carbon Neutral Energy Res WPI 12CNER, Nishi Ku, Motooka 744, Fukuoka, Fukuoka 8190395, Japan;

Kyushu Univ, Grad Sch Sci, Dept Chem, Nishi Ku, Motooka 744, Fukuoka, Fukuoka 8190395, Japan;

RIKEN, SPring 8 Ctr, 1-1-1 Kouto, Mikazuki, Hyogo 6795148, JapanSanyo Onoda City Univ, Fac Engn, Dept Appl Chem, Daigakudo Ri 1-1-1, Sanyo Onoda, Yamaguchi 7560884, Japan;

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正文语种英语
中图分类汉语教学;
关键词
Refractive surgery enhancement; Catalysis; ELECTROWINNINGHydroxyacetic Acidspower storagecomposite controlAlcoholicsPair distribution functionOxalic AcidHydrogenationoxides;

机译：屈光手术增强;催化;ELECTROWINNINGHydroxyaceticAcidspower storagecomposite controlAlcoholicsPair分布functionOxalicAcidHydrogenationoxides;

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Catalytic enhancement on Ti-Zr complex oxide particles for electrochemical hydrogenation of oxalic acid to produce an alcoholic compound by controlling electronic states and oxide structures

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