Palladium doping of In2O3 towards a general and selective catalytic hydrogenation of amides to amines and alcohols

Sorribes Ivan; Lemos Samantha C. S.; Martin SantiagoMayoral AlvaroLima Renata C.Andres Juan

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Palladium doping of In2O3 towards a general and selective catalytic hydrogenation of amides to amines and alcohols

机译：对一位将军和钯掺杂的研究选择性催化加氢的酰胺胺类和醇类

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Herein, the first general heterogeneous catalytic protocol for the hydrogenation of primary, secondary and tertiary amides to their corresponding amines and alcohols is described. Advantageously, this catalytic protocol works under additive-free conditions and is compatible with the presence of aromatic rings, which are fully retained in the final products. This hydrogenative C-N bond cleavage methodology is catalyzed by a Pd-doped In2O3 catalyst prepared by a microwave hydrothermal-assisted method followed by calcination. This catalyst displays highly dispersed Pd2+ ionic species in the oxide matrix of In2O3 that have appeared to be essential for its high catalytic performance.

机译：这里,第一个通用异构催化协议主要的加氢,二级和三级酰胺相应的胺类和醇类。有利地,这种催化协议有效在精细条件下和兼容与芳香环的存在完全保留在最终的产品。氢解碳氮键解理方法催化剂催化的Pd-doped研究准备由微波hydrothermal-assisted方法其次是煅烧。高度分散Pd2 +氧化离子物种矩阵的研究似乎其高催化性能的必要条件。

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来源
《Catalysis science & technology》 |2019年第24期|6965-6976|共12页
作者
Sorribes Ivan; Lemos Samantha C. S.; Martin SantiagoMayoral AlvaroLima Renata C.Andres Juan;
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作者单位

Univ Fed Uberlandia, Inst Quim, BR-38400902 Uberlandia, MG, Brazil;

ShanghaiTech Univ, Ctr High Resolut Electron Microscopy ChEM, Sch Phys Sci & Technol, 393 Middle Huaxia Rd, Shanghai 201210, Peoples R China;

Univ Jaume 1, Dept Quim Fis & Analit, Av Sos Baynat S-N, Castellon de La Plana 12071, SpainUniv Zaragoza, Dept Quim Fis, Fac Ciencias, ICMA,CSIC, E-50009 Zaragoza, Spain;

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正文语种英语
中图分类汉语教学;
关键词
Catalysis; Amines; Hydrogenationamides;

机译：催化;胺类;Hydrogenationamides;

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Palladium doping of In2O3 towards a general and selective catalytic hydrogenation of amides to amines and alcohols

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