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首页> 外文期刊>Catalysis science & technology >Direct access to N-alkylated amines and imines via acceptorless dehydrogenative coupling catalyzed by a cobalt(ii)-NNN pincer complex
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Direct access to N-alkylated amines and imines via acceptorless dehydrogenative coupling catalyzed by a cobalt(ii)-NNN pincer complex

机译:直接访问N-alkylated胺和亚胺通过acceptorless dehydrogenative耦合催化钴(ii) nnn螯复杂

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摘要

A simple, phosphine-free Co(ii)-NNN pincer complex catalyzed direct N-alkylation of anilines with alcohols via hydrogen auto-transfer (HA) and selective acceptorless dehydrogenative coupling (ADC) of benzylamines with alcohols affording imines with the liberation of molecular hydrogen and water is reported.
机译:一个简单的、phosphine-free有限公司(ii) nnn螯复杂催化直接N-alkylation苯胺类氢醇通过自动传送(HA)和选择性acceptorless dehydrogenative耦合(ADC)苄胺与醇类提供亚胺与氢分子的解放报告和水。

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