Phosphine-free cobalt pincer complex catalyzed Z-selective semi-hydrogenation of unbiased alkynes

Landge Vinod G.; Pitchaimani Jayaraman; Midya Siba P.Subaramanian MuruganMadhu VedichiBalaraman Ekambaram

首页> 外文期刊>Catalysis science & technology >Phosphine-free cobalt pincer complex catalyzed Z-selective semi-hydrogenation of unbiased alkynes

【24h】

Phosphine-free cobalt pincer complex catalyzed Z-selective semi-hydrogenation of unbiased alkynes

机译：Phosphine-free钴螯复杂的催化Z-selective semi-hydrogenation的公正的炔烃

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

Herein, we report a novel, molecularly defined NNN-type cobalt pincer complex catalyzed transfer semi-hydrogenation of unbiased alkynes to Z-selective alkenes. This unified process is highly stereo-and chemo-selective and exhibits a broad scope as well as wide functional group tolerance. Ammonia-borane (AB), a bench-stable substrate with high gravimetric hydrogen capacity, was used as a safe and practical transfer hydrogenating source.

机译：在此,我们报告一个小说,分子的定义NNN-type螯复杂钴催化转移semi-hydrogenation无偏炔烃Z-selective烯烃。高度音响和chemo-selective和展览广泛的范围宽以及官能团宽容。基质重量高的氢能力,被用作安全实用转移加氢,来源。

著录项

来源
《Catalysis science & technology》 |2018年第2期|428-433|共6页
作者
Landge Vinod G.; Pitchaimani Jayaraman; Midya Siba P.Subaramanian MuruganMadhu VedichiBalaraman Ekambaram;
展开▼
作者单位

Karunya Univ, Dept Chem, Coimbatore 641114, Tamil Nadu, India;

Natl Chem Lab, CSIR, Catalysis Div, Dr Homi Bhabha Rd, Pune 411008, Maharashtra, India;

展开▼
收录信息
原文格式 PDF
正文语种英语
中图分类
关键词
alkynes; unbiasedness; Safescapacity of hydrogen storage;

机译：炔烃;无偏性;Safescapacity的氢存储;

相似文献

外文文献
中文文献

1. A Novel Synthesis of Dimethyl Malonate by Carbonylation of Methyl Chloroacetate Catalyzed by Cobalt Complex [J] . 中国化学快报（英文版） . 2001,第003期
2. Ab Initio MO Studies on the Reaction Mechanism for Carbonyl Insertion Catalyzed by Carbonyl Cobalt Complex [J] . 高等学校化学研究（英文版） . 2000,第001期
3. Structural and Kinetics Understanding of Support Effects in Pd-Catalyzed Semi-Hydrogenation of Acetylene [J] . Yueqiang Cao, Xiaohu Ge, Yurou Li, 工程（英文） . 2021,第001期
4. Structural and Kinetics Understanding of Support Effects in Pd-Catalyzed Semi-Hydrogenation of Acetylene [J] . Yueqiang Cao, Xiaohu Ge, Yurou Li, 工程（英文） . 2021,第001期
5. Pincer cobalt complex-catalyzed Z-selective hydrosilylation of terminal alkynes [J] . Xiaoyong Du, Wenjun Hou, Yanlu Zhang Organic Chemistry Frontiers . 2017,第8期

机译：螯钴complex-catalyzed Z-selective氢化硅烷化的终端炔烃
6. Z-Selective alkyne semi-hydrogenation catalysed by piano-stool N-heterocyclic carbene iron complexes [J] . Johnson Chloe, Albrecht Martin Catalysis science & technology . 2018,第11期

机译：Z-Selective炔semi-hydrogenation催化了琴凳上氮杂卡宾铁配合物
7. Cobalt-catalyzed hydrogen desorption from the LiNH2–LiBH4 system [O] . Henderson, William, Linklater, Rachael A., Cameron, Nicola E., 2008

机译：Cobalt-catalyzed hydrogen desorption from the LiNH2–LiBH4 system

Phosphine-free cobalt pincer complex catalyzed Z-selective semi-hydrogenation of unbiased alkynes

摘要

著录项

相似文献

相关主题

期刊订阅