High-throughput evaluation of in situ-generated cobalt(III) catalysts for acyl fluoride synthesis

Lee Graham M.; Clement Roxanne; Baker R. Tom

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High-throughput evaluation of in situ-generated cobalt(III) catalysts for acyl fluoride synthesis

机译：高通量situ-generated评价(3)钴催化剂酰基氟合成

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Using a high-throughput experimental procedure, a series of cobalt(III) complexes of the general formula (CpCo)-Co-R(I)(X)(L) were prepared and screened for their activity towards the catalytic nucleophilic fluorination of benzoyl chloride. A highly active catalyst was identified, and successfully employed in a mild and effective protocol for the synthesis of a group of acyl fluoride compounds.

机译：使用高通量实验过程,钴系列(3)复合物的将军公式(CpCo) -Co-R (I) (X) (L)和准备他们的活动对催化筛查苯甲酰氯的亲核氟化。高活性催化剂被发现成功地采用温和的和有效的协议的合成酰基氟化合物。

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《Catalysis science & technology》 |2017年第21期|4996-5003|共8页
作者
Lee Graham M.; Clement Roxanne; Baker R. Tom;
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作者单位

Univ Ottawa, Dept Chem & Biomol Sci, 30 Marie Curie, Ottawa, ON K1N 6N5, Canada;

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原文格式 PDF
正文语种英语
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关键词
Fluorination; Efficient Protocol; benzoyl chlorideCatalystssynthesis;

机译：氟化;有效协议;苯甲酰chlorideCatalystssynthesis;

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High-throughput evaluation of in situ-generated cobalt(III) catalysts for acyl fluoride synthesis

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