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Simultaneous removal of elemental mercury and NO from simulated flue gas using a CeO2 modified V2O5-WO3/TiO2 catalyst

机译:同时去除汞元素,也没有从模拟烟气使用CeO2修改V2O5-WO3 /二氧化钛催化剂

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摘要

To provide insight into optimizing flue gas treatment, simultaneous removal of elemental mercury (Hg-0) and NO using a CeO2 modified V2O5-WO3/TiO2 catalyst was investigated. The results show that a novel V2O5-WO3/TiO2-CeO2 catalyst exhibits excellent Hg-0 oxidation efficiency (88%) and NO conversion efficiency (89%) at 250 degrees C. Furthermore, CeO2 modified V2O5-WO3/TiO2 not only exhibits enhanced catalytic activity but also good resistance in SO2 and H2O. These catalysts were also characterized using BET, SEM, XRD, XPS, and H-2-TPR. We found lower crystallinity, more reduced species and better texture properties to be presented, which were all ascribed to CeO2 doping. Also, the redox cycle (V4+ + Ce4+ V5+ + Ce3+) plays a key role in promoting Hg-0 oxidation and NO conversion. In tune with the experimental results, a mechanism for the simultaneous removal of Hg-0 and NO was proposed for the V2O5-WO3/TiO2-CeO2 catalysts.
机译:提供洞察优化烟气治疗,同时删除元素汞(Hg-0)和没有使用CeO2修改V2O5-WO3 /二氧化钛催化剂进行了研究。结果表明,一种新型V2O5-WO3 / TiO2-CeO2展示优秀的Hg-0氧化催化剂效率(88%)和转换效率(89%)在250度c .此外,CeO2修改V2O5-WO3 /二氧化钛不仅展品增强催化活性也是良好的阻力二氧化硫和水。使用特征选择,SEM, XRD, XPS,H-2-TPR。减少物种和更好的纹理特性介绍,这都归因于CeO2兴奋剂。+ Ce3 +)在促进Hg-0起着关键作用氧化和转换。实验结果的机制同时删除Hg-0也没有了V2O5-WO3 / TiO2-CeO2催化剂。

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