Hydration of aromatic alkynes catalyzed by a self-assembled hexameric organic capsule

La Sorella Giorgio; Sperni Laura; Ballester PabloStrukul GiorgioScarso Alessandro

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Hydration of aromatic alkynes catalyzed by a self-assembled hexameric organic capsule

机译：催化芳香炔烃的水合作用自组装有机hexameric胶囊

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The combination of a Bronsted acid catalyst and a supramolecular organic capsule formed by the self-assembly of six resorcin[ 4] arene units efficiently promotes the mild hydration of aromatic alkynes to their corresponding ketones. The capsule provides a suitable nanoenvironment that favors protonation of the substrate and addition of water.

机译：的组合和布仑斯惕酸催化剂超分子有机形成的胶囊自组装的六间苯二酚[4]芳烃单元有效地促进了轻微的水化芳香炔烃相应的酮。胶囊提供合适的nanoenvironment有利于质子化作用的底物添加水。

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来源
《Catalysis science & technology》 |2016年第15期|6031-6036|共6页
作者
La Sorella Giorgio; Sperni Laura; Ballester PabloStrukul GiorgioScarso Alessandro;
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作者单位

Univ Ca Foscari Venezia, Dipartimento Sci Mol & Nanosistemi, Via Torino 155, I-30172 Venice, Italy;

Barcelona Inst Sci & Technol, Inst Res & Adv Studies ICREA, Avgda Paisos Catalans 16, Tarragona 43007, Spain;

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正文语种英语
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关键词
alkynes; Hydration; Bronsted acidsCAPSULESorganic;

机译：炔烃;水化;布仑斯惕acidsCAPSULESorganic;

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Hydration of aromatic alkynes catalyzed by a self-assembled hexameric organic capsule

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