Trifluoromethylation of thiophenols and thiols with sodium trifluoromethanesulfinate and iodine pentoxide

Ma Jing-Jing; Yi Wen-Bin; Lu Guo-PingCai Chun

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Trifluoromethylation of thiophenols and thiols with sodium trifluoromethanesulfinate and iodine pentoxide

机译：Trifluoromethylation苯硫酚和硫醇trifluoromethanesulfinate钠和碘五氧化二

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摘要

A selective and facile trifluoromethylation process for a wide range of thiophenols and thiols under metal free conditions has been developed using two simple and safe solids, sodium trifluoro-methanesulfinate and iodine pentoxide, via the radical process.

机译：选择性和肤浅trifluoromethylation广泛的苯硫酚和过程金属自由条件下硫醇使用两个简单的开发和安全的固体,钠trifluoro-methanesulfinate和碘五氧化二,通过激进的过程。

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来源
《Catalysis science & technology》 |2016年第2期|417-421|共5页
作者
Ma Jing-Jing; Yi Wen-Bin; Lu Guo-PingCai Chun;
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作者单位

Nanjing Univ Sci & Technol, Sch Chem Engn, Nanjing 210094, Jiangsu, Peoples R China;

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正文语种英语
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关键词
METAL-FREE; Sulfhydryl Compounds; iodine pentoxidethiophenol;

机译：不含金属的;巯基化合物;碘pentoxidethiophenol;

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外文文献

1. Trifluoromethylation of Carbonyl Compounds with Sodium Trifluoroacetate [J] . 中国化学快报（英文版） . 2005,第010期
2. Human sodium/iodide symporter gene induced iodine uptake in human lung adenocarcinoma via baculovirus [J] . GUO Rui, ZHANG Yifan, LIANG Sheng, 核技术：英文版 . 2010,第002期
3. Human sodium/iodide symporter gene induced iodine uptake in human lung adenocarcinoma via baculovirus [J] . GUO Rui, ZHANG Yifan, LIANG Sheng, 核技术（英文版） . 2010,第002期

Trifluoromethylation of thiophenols and thiols with sodium trifluoromethanesulfinate and iodine pentoxide

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